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Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal
G. Q. Qu; W. C. Zheng; H. G. Liu; W. Q. Yang
2009
发表期刊Molecular Physics
ISSN0026-8976
卷号107期号:23-24页码:2551-2554
摘要The spin-Hamiltonian parameters (g factor g//, g perpendicular to and hyperfine structure constants A//, A perpendicular to) for Er3+ ion at the trigonal Al3+ site of AlN crystal are calculated by diagonalising the 52 x 52 energy matrix. The matrix are related to the ground mutiplet 4I15/2 and the first to third excited multiplets 4I13/2, 4I11/2 and 4I9/2 for 4f11 ions in trigonal crystal field under an external magnetic field. The crystal-field parameters used in the matrix are obtained from the superposition model and the local lattice relaxation due to the substitution of Er3+ for Al3+ is considered. The calculated spin-Hamiltonian parameters are in reasonable agreement with the experimental values and the signs of hyperfine structure constants are suggested. The results are discussed.
部门归属[qu, gui-qiang; zheng, wen-chen; liu, hong-gang; yang, wei-qing] sichuan univ, dept mat sci, chengdu 610064, peoples r china. [yang, wei-qing] chengdu univ informat & technol, dept opt & elect, chengdu 610225, peoples r china. [zheng, wen-chen] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwc1@163.com
关键词Spin-hamiltonian Parameters Crystal-field Theory Diagonalisation (Of Energy Matrix) Method Er3++ Aln Superposition-model Analysis Epr Parameters Single-crystals Gan Erbium Ion Er Resonance Garnet
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WOS记录号WOS:000272898000013
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/32250
专题中国科学院金属研究所
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GB/T 7714
G. Q. Qu,W. C. Zheng,H. G. Liu,et al. Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal[J]. Molecular Physics,2009,107(23-24):2551-2554.
APA G. Q. Qu,W. C. Zheng,H. G. Liu,&W. Q. Yang.(2009).Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal.Molecular Physics,107(23-24),2551-2554.
MLA G. Q. Qu,et al."Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal".Molecular Physics 107.23-24(2009):2551-2554.
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