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Substitutional site and defect structure of Ni2+ in LiNbO3 crystal studied from the optical and electron paramagnetic resonance spectra
W. L. Feng; X. X. Wu; W. C. Zheng
2008
Source PublicationRadiation Effects and Defects in Solids
ISSN1042-0150
Volume163Issue:1Pages:29-34
AbstractThe energy levels (which are related to optical spectra) and effective spin-Hamiltonian parameters (g factors g(//) g(perpendicular to) and zero-field splitting D which are measured by electron paramagnetic resonance (EPR) spectra) of Ni2+ ion in LiNbO3 are calculated from the complete diagonalization (of energy matrix) method. In the calculations, the Ni2+ ion is suggested to replace Li+ ion with the local relaxation in LiNbO3. This point is in disagreement with the opinions in many previous papers in which the substitutional site and structural data of Ni2+ at Nb5+ site are used to explain the experimental data obtained by the optical and EPR spectra. The present calculated results are also consistent with the experimental values. The reasonableness of the substitutional site and defect structure of Ni2+ at Li+ site is discussed.
description.department[feng, wen-lin] chongqing inst technol, dept appl phys, chongqing 400050, peoples r china. [feng, wen-lin; wu, xiao-xuan; zheng, wen-chen] sichuan univ, dept mat sci, chengdu 610064, peoples r china. [wu, xiao-xuan] civil aviat flying inst china, dept phys, guanghan 618307, peoples r china. [wu, xiao-xuan; zheng, wen-chen] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;feng, wl (reprint author), chongqing inst technol, dept appl phys, chongqing 400050, peoples r china;wenlinfeng@126.com
KeywordDefect Structure Optical Spectra Epr Spectra Complete Diagonalization Method Ni2++ Linbo3 Spin-hamiltonian Parameters C-3 Symmetry Cr3++ Ions Field Epr Litao3 Impurities Absorption Holograms Centers
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WOS IDWOS:000251837800004
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/32754
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
W. L. Feng,X. X. Wu,W. C. Zheng. Substitutional site and defect structure of Ni2+ in LiNbO3 crystal studied from the optical and electron paramagnetic resonance spectra[J]. Radiation Effects and Defects in Solids,2008,163(1):29-34.
APA W. L. Feng,X. X. Wu,&W. C. Zheng.(2008).Substitutional site and defect structure of Ni2+ in LiNbO3 crystal studied from the optical and electron paramagnetic resonance spectra.Radiation Effects and Defects in Solids,163(1),29-34.
MLA W. L. Feng,et al."Substitutional site and defect structure of Ni2+ in LiNbO3 crystal studied from the optical and electron paramagnetic resonance spectra".Radiation Effects and Defects in Solids 163.1(2008):29-34.
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