Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition

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	Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition
	H. J. Wang; X. Z. Hong; F. Gu; X. W. Ba
	2006
发表期刊	Science in China Series B-Chemistry
ISSN	1006-9291
卷号	49 期号:6 页码:499-506
摘要	The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A(a)D(d) type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed.
部门归属	hebei univ, coll chem & environm sci, baoding 071002, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn
关键词	Hydrogen Bonding Fluid Equilibrium Free Energy Geometrical Phase Transition Equation-of-state Thermoreversible Gelation Liquid Water Computer-simulations Dynamics Networks Polymers Models
URL	查看原文
WOS记录号	WOS:000244104200003
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/34503
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. J. Wang,X. Z. Hong,F. Gu,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition[J]. Science in China Series B-Chemistry,2006,49(6):499-506.
APA	H. J. Wang,X. Z. Hong,F. Gu,&X. W. Ba.(2006).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition.Science in China Series B-Chemistry,49(6),499-506.
MLA	H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition".Science in China Series B-Chemistry 49.6(2006):499-506.