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Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution
X. Yang; S. Chen; C. Wang; L. Li
2006
发表期刊Russian Journal of Electrochemistry
ISSN1023-1935
卷号42期号:5页码:491-496
摘要Potentiostatic current oscillation of iron electrode in 0.5 mol/l sulfuric acid solution in half open microenvironment is studied. Results show that the microenvironment at the vicinity of the electrode has an important effect on current oscillation. The rate of mass transport of the Fe2+ and H+ can influence the oscillation period: the more difficult the migration of the Fe2+ and H+ ions, the longer the oscillation period. Digital holography is used to study the dynamic changes at the electrode/solution interface during current oscillation. This new method offers a new approach to studying the influence of mass transport on current oscillation.
部门归属state key lab corros & protect, shenyang 110015, peoples r china. shandong univ, jinan 250100, peoples r china. xuzhou normal univ, xuzhou 221009, peoples r china.;chen, s (reprint author), state key lab corros & protect, shenyang 110015, peoples r china;shchen@sdu.edu.cn
关键词Current Oscillation Iron Electrode Microenvironment Mass Transport Digital Holography Franck-fitzhugh Model Holographic Microphotography Electrochemical Reaction Solution Interfaces Electrodissolution Dissolution Stability Dynamics System
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WOS记录号WOS:000237772000006
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34647
专题中国科学院金属研究所
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X. Yang,S. Chen,C. Wang,et al. Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution[J]. Russian Journal of Electrochemistry,2006,42(5):491-496.
APA X. Yang,S. Chen,C. Wang,&L. Li.(2006).Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution.Russian Journal of Electrochemistry,42(5),491-496.
MLA X. Yang,et al."Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution".Russian Journal of Electrochemistry 42.5(2006):491-496.
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