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Statistical mechanics and reaction dynamics theory for polycondensations
H. J. Wang; X. Z. Hong; X. W. Ba
2005
发表期刊Chemical Journal of Chinese Universities-Chinese
ISSN0251-0790
卷号26期号:11页码:2077-2081
摘要By the investigations of two types of representative polycondensations from statistical theory and dynamics, the relationship between the dynamics and statistics of the system under consideration is pointed out. Based on this, we obtain the explicit relationship between the conversions and equilibrium dynamical constant and reaction free energy, by which the characterization of the average polymer physical quantities can further be simplified. Moreover, the influences of temperature and pressure on the polymerization process are discussed.
部门归属hebei univ, coll chem & environm sci, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn
关键词Polycondensations Statistical Mechanics Equilibrium Reaction Dynamics Molecular-size Distribution Equilibrium Polymerization Monomers Polymers
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WOS记录号WOS:000233392400024
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35071
专题中国科学院金属研究所
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GB/T 7714
H. J. Wang,X. Z. Hong,X. W. Ba. Statistical mechanics and reaction dynamics theory for polycondensations[J]. Chemical Journal of Chinese Universities-Chinese,2005,26(11):2077-2081.
APA H. J. Wang,X. Z. Hong,&X. W. Ba.(2005).Statistical mechanics and reaction dynamics theory for polycondensations.Chemical Journal of Chinese Universities-Chinese,26(11),2077-2081.
MLA H. J. Wang,et al."Statistical mechanics and reaction dynamics theory for polycondensations".Chemical Journal of Chinese Universities-Chinese 26.11(2005):2077-2081.
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