Statistical mechanics and reaction dynamics theory for polycondensations | |
H. J. Wang; X. Z. Hong; X. W. Ba | |
2005 | |
发表期刊 | Chemical Journal of Chinese Universities-Chinese
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ISSN | 0251-0790 |
卷号 | 26期号:11页码:2077-2081 |
摘要 | By the investigations of two types of representative polycondensations from statistical theory and dynamics, the relationship between the dynamics and statistics of the system under consideration is pointed out. Based on this, we obtain the explicit relationship between the conversions and equilibrium dynamical constant and reaction free energy, by which the characterization of the average polymer physical quantities can further be simplified. Moreover, the influences of temperature and pressure on the polymerization process are discussed. |
部门归属 | hebei univ, coll chem & environm sci, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn |
关键词 | Polycondensations Statistical Mechanics Equilibrium Reaction Dynamics Molecular-size Distribution Equilibrium Polymerization Monomers Polymers |
URL | 查看原文 |
WOS记录号 | WOS:000233392400024 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35071 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. J. Wang,X. Z. Hong,X. W. Ba. Statistical mechanics and reaction dynamics theory for polycondensations[J]. Chemical Journal of Chinese Universities-Chinese,2005,26(11):2077-2081. |
APA | H. J. Wang,X. Z. Hong,&X. W. Ba.(2005).Statistical mechanics and reaction dynamics theory for polycondensations.Chemical Journal of Chinese Universities-Chinese,26(11),2077-2081. |
MLA | H. J. Wang,et al."Statistical mechanics and reaction dynamics theory for polycondensations".Chemical Journal of Chinese Universities-Chinese 26.11(2005):2077-2081. |
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