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Diffusion of chromium in nanocrystalline iron produced by means of surface mechanical attrition treatment
Z. B. Wang; N. R. Tao; W. P. Tong; J. Lu; K. Lu
2003
Source PublicationActa Materialia
ISSN1359-6454
Volume51Issue:14Pages:4319-4329
AbstractBy means of surface mechanical attrition treatment (SMAT) to a pure iron plate, a nanometer-grained surface layer without porosity and contamination was fabricated. The average grain size in the top surface layer (of 5 mum thick) is about 10-25 nm, and the grain size stability can be maintained up to 653 K. Cr diffusion kinetics in the nanocrystalline Fe phase was measured by using second ion mass spectrometry within a temperature range of 573-653 K. Experimental results showed that diffusivity of Cr in the nanocrystalline Fe is 7-9 orders of magnitude higher than that in Fe lattice and 4-5 orders of magnitude higher than that in the grain boundaries (GBs) of alpha-Fe. The activation energy for Cr diffusion in the Fe nanophase is comparable to that of the GB diffusion, but the pre-exponential factor is much higher. The enhanced diffusivity of Cr may originate from a large volume fraction of non-equilibrium GBs and a considerable amount of triple junctions in the present nanocrystalline Fe sample processed by means of the SMAT technique. (C) 2003 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
description.departmentchinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. univ technol troyes, lasmis, f-10000 troyes, france.;lu, k (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china
KeywordNanocrystalline Surface Mechanical Attrition Treatment Thermal Stability Diffusion Grain Boundary Grain-boundary Diffusion Positron-lifetime Copper Alloys Spectroscopy Hydrogen Nickel Metals Layer
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WOS IDWOS:000184761600027
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Cited Times:280[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/36068
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Z. B. Wang,N. R. Tao,W. P. Tong,et al. Diffusion of chromium in nanocrystalline iron produced by means of surface mechanical attrition treatment[J]. Acta Materialia,2003,51(14):4319-4329.
APA Z. B. Wang,N. R. Tao,W. P. Tong,J. Lu,&K. Lu.(2003).Diffusion of chromium in nanocrystalline iron produced by means of surface mechanical attrition treatment.Acta Materialia,51(14),4319-4329.
MLA Z. B. Wang,et al."Diffusion of chromium in nanocrystalline iron produced by means of surface mechanical attrition treatment".Acta Materialia 51.14(2003):4319-4329.
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