Defect model of a tetragonal Sm3+ center found from EPR measurements in CaF2 and SrF2 crystals | |
W. C. Zheng; H. N. Dong; S. Y. Wu; S. Tang | |
2003 | |
发表期刊 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
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ISSN | 0932-0784 |
卷号 | 58期号:5-6页码:373-375 |
摘要 | The EPR parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants A(parallel to), A(perpendicular to)) of a tetragonal (C-4v) Sm3+ center in CaF2 and SrF2 crystals are calculated by considering the crystal-field J-mixing among the ground H-6(5/2), the first excited H-6(7/2) and second excited H-6(9/2) state multiplets. In the calculations the free-ion and crystal-field parameters of the tetragonal Sm3+-F- center obtained from polarized laser-selective excitation spectroscopy are used. The calculated results suggest that the tetragonal Sm3+-F- center is the Sm3+ center found by later EPR measurements. The g factors g(parallel to), g(perpendicular to) and hyperfine structure constants A(parallel to), A(perpendicular to) of this EPR center are satisfactorily explained. |
部门归属 | sichuan univ, dept mat sci, chengdu 610064, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. sichuan normal univ, inst solid state phys, chengdu 610066, peoples r china. univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china |
关键词 | Defect Model Electron Paramagnetic Resonance Crystal-field Theory Sm3++ Caf2 Srf2 Electron-paramagnetic-resonance Trivalent Rare-earth Calcium Fluoride Ions |
URL | 查看原文 |
WOS记录号 | WOS:000184274600020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/36208 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,H. N. Dong,S. Y. Wu,et al. Defect model of a tetragonal Sm3+ center found from EPR measurements in CaF2 and SrF2 crystals[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2003,58(5-6):373-375. |
APA | W. C. Zheng,H. N. Dong,S. Y. Wu,&S. Tang.(2003).Defect model of a tetragonal Sm3+ center found from EPR measurements in CaF2 and SrF2 crystals.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,58(5-6),373-375. |
MLA | W. C. Zheng,et al."Defect model of a tetragonal Sm3+ center found from EPR measurements in CaF2 and SrF2 crystals".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 58.5-6(2003):373-375. |
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