Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy

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	Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy; Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy
	J. Ma; X. Jiang; L. C. Jiang; M. Q. Lu
	1996 ; 1996
发表期刊	Acta Physico-Chimica Sinica ; Acta Physico-Chimica Sinica
ISSN	1000-6818 ; 1000-6818
卷号	12 期号:1 页码:22-28
摘要	The electrochemical behaviours of the hydrogen evolution reaction (HER) on electrodes prepared by composite coating of nanocrystalline Ni-Mo alloy particle which was formed by ball milling on nickel base has been studied by steady-state polarization and ac impedance techniques. The microstructure and the particle size of Ni-Mo alloy nanocrystals and the morphology of the composite-coated surface of the electrodes were examined by XRD, TEM and SEM. The mechanism of HER on the composite electrodes has been investigated as well. Results showed that for HER electrocatalytic activity which was enhanced with increasing milling time. The reaction rate of HER on the electrodes was proved to be controlled by electrodesorption. The direct composite coating of highly electroactive particles onto the surface may serve as a new approach to the preparation of electrode materials.; The electrochemical behaviours of the hydrogen evolution reaction (HER) on electrodes prepared by composite coating of nanocrystalline Ni-Mo alloy particle which was formed by ball milling on nickel base has been studied by steady-state polarization and ac impedance techniques. The microstructure and the particle size of Ni-Mo alloy nanocrystals and the morphology of the composite-coated surface of the electrodes were examined by XRD, TEM and SEM. The mechanism of HER on the composite electrodes has been investigated as well. Results showed that for HER electrocatalytic activity which was enhanced with increasing milling time. The reaction rate of HER on the electrodes was proved to be controlled by electrodesorption. The direct composite coating of highly electroactive particles onto the surface may serve as a new approach to the preparation of electrode materials.
部门归属	[ma jie] capital normal univ, dept chem, beijing 100037, peoples r china. [jiang xiong; jiang lincai] s china normal univ, dept chem, guangzhou 510631, guangdong, peoples r china. [lue manqi] acad sinica, inst met res, state key lab rapidly solidified nonequilibrium, shenyang 110006, peoples r china.;ma, j (reprint author), capital normal univ, dept chem, beijing 100037, peoples r china ; [ma jie] capital normal univ, dept chem, beijing 100037, peoples r china. [jiang xiong; jiang lincai] s china normal univ, dept chem, guangzhou 510631, guangdong, peoples r china. [lue manqi] acad sinica, inst met res, state key lab rapidly solidified nonequilibrium, shenyang 110006, peoples r china.;ma, j (reprint author), capital normal univ, dept chem, beijing 100037, peoples r china
关键词	Composite Coating Composite Coating Hydrogen Evolution Reaction Hydrogen Evolution Reaction Nanocrystalline Nanocrystalline Ni-mo Ni-mo Alloy Alloy Ball Milling Ball Milling
URL	查看原文 ; 查看原文
WOS记录号	WOS:000207591300006 ; WOS:000207591300006
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/38366
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. Ma,X. Jiang,L. C. Jiang,et al. Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy, Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy[J]. Acta Physico-Chimica Sinica, Acta Physico-Chimica Sinica,1996, 1996,12, 12(1):22-28, 22-28.
APA	J. Ma,X. Jiang,L. C. Jiang,&M. Q. Lu.(1996).Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy.Acta Physico-Chimica Sinica,12(1),22-28.
MLA	J. Ma,et al."Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Mo Alloy".Acta Physico-Chimica Sinica 12.1(1996):22-28.