In this paper, a simple and uniform method of calculating the zero-field splitting D (7) in the tetragonal phase from the spin-lattice coupling' coefficient G11 in the cubic phase for all d'' ions in crystals with the perovskite structure has been established. Based on this, the zero-field splitting D (7) for Ni2+ ion in the tetragonal phase of a RbCdF3 crystal is calculated by using the parameters obtained from the optical spectra and the isotropic g factor. The result shows reasonable agreement with the experimental findings.
部门归属
acad sinica,int ctr mat phys,shenyang 110015,peoples r china.;zheng, wc (reprint author), sichuan univ,dept mat sci,chengdu 610064,peoples r china
W. C. Zheng. THEORETICAL EXPLANATION OF THE EPR-SPECTRA FOR NI2+ IONS IN THE TETRAGONAL PHASE OF A RBCDF3 CRYSTAL[J]. Physical Review B,1994,49(10):7029-7031.
APA
W. C. Zheng.(1994).THEORETICAL EXPLANATION OF THE EPR-SPECTRA FOR NI2+ IONS IN THE TETRAGONAL PHASE OF A RBCDF3 CRYSTAL.Physical Review B,49(10),7029-7031.
MLA
W. C. Zheng."THEORETICAL EXPLANATION OF THE EPR-SPECTRA FOR NI2+ IONS IN THE TETRAGONAL PHASE OF A RBCDF3 CRYSTAL".Physical Review B 49.10(1994):7029-7031.
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