THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL

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	THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL
	Z. Wenchen
	1993
发表期刊	Journal of Physics and Chemistry of Solids
ISSN	0022-3697
卷号	54 期号:11 页码:1587-1592
摘要	In order to overcome the difficulties in explaining the zero-field splitting and its stress (along the C3 axis) and hydrostatic pressure dependence for Na2ZnCl4.3H2O:Mn2+ crystal, which arise in previous work, we assume, in this paper, that the Mn2+ ion does not occupy the exact substitutional position of Zn2+ ion in Na2ZnCl4-3H2O, but is displaced about 0.3 angstrom on the C3 axis. Based on this, the zero-field splitting and its stress and pressure dependence have been calculated using the superposition model (and also the spin-orbit coupling mechanism), the results show reasonable agreement with the experimental findings.
部门归属	acad sinica,int ctr mat phys,shenyang 110015,peoples r china.
关键词	Electron Paramagnetic Resonance Superposition Model Local Lattice Relaxation Mn2++ Ion Na2zncl43h2o S-6-state Ions Parameters Symmetry Spectra Linbo3 Site
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/39149
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Z. Wenchen. THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL[J]. Journal of Physics and Chemistry of Solids,1993,54(11):1587-1592.
APA	Z. Wenchen.(1993).THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL.Journal of Physics and Chemistry of Solids,54(11),1587-1592.
MLA	Z. Wenchen."THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL".Journal of Physics and Chemistry of Solids 54.11(1993):1587-1592.