| Structure and hydrogen absorbing properties of ScCrMn alloy | |
| W. H. Li; E. D. Wu | |
| 2012 | |
| Source Publication | Journal of Alloys and Compounds
 |
| ISSN | 0925-8388 |
| Volume | 511Issue:1Pages:169-175 |
| Abstract | The crystal structures of ScCrMn alloy and its hydride are determined by XRD Rietveld analysis and TEM examination. The ScCrMn alloy exhibits a rarely ideal close-packed C14 type hexagonal Laves phase structure with lattice parameters a = 5.064(1), c = 8.263(2) angstrom, deviating from the ANOE dependent rule on Laves phase structure. The hydrogenation of the alloy to ScCrMnH(3.9) results in significant lattice expansion of 27%, but does not alter the matrix lattice structure. The XRD pattern of the hydride also shows close-packed structure with little line broadening, comparable to that of the alloy, indicating a high degree of crystallinity, where the hydrogen atoms are homogeneously distributed in evenly distributed interstitials with minimal defects. The alloy demonstrates extremely easy activation property. The alloy can be activated at a low pressure of 0.46 kPa and exhibit very fast absorption rate at sub-atmosphere at room temperature. The hydrogenation thermodynamics of the alloy are evaluated by P-C-T measurements at different temperatures. At hydrogen concentration H/M = 0.66 corresponding to a defined room temperature plateau pressure, the relative partial molar enthalpy Delta H and entropy Delta S derived by Van't Hoff equation are -63 kJ/mol and -111 J/mol K, respectively. These results manifest that the hydride stability of the ScCrMn alloy is comparable to those of the hydrogen isotope storage alloys of ZrCo and ZrTi(0.2)V(1.8), and would be superior on relevant applications. The DSC-TG measurements of the hydride reveal that the total release of hydrogen can basically be achieved at 653 K, accompanied by an oxidation reaction with residual oxygen to form water vapor. The results indicate that the alloy is an effective catalyst for the dissociation of hydrogen and combination of oxygen. (C) 2011 Elsevier B.V. All rights reserved. |
| description.department | [li, wuhui; wu, erdong] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;wu, ed (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china.;ewu@imr.ac.cn |
| Keyword | Sc-based Laves Phase Alloy Crystal Structure Hydrogen Activation Hydrogen Absorption/desorption Thermodynamics Laves Phase Alloys Crystal-structure Equilibrium Systems |
| URL | 查看原文 |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/60071 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | W. H. Li,E. D. Wu. Structure and hydrogen absorbing properties of ScCrMn alloy[J]. Journal of Alloys and Compounds,2012,511(1):169-175. |
| APA | W. H. Li,&E. D. Wu.(2012).Structure and hydrogen absorbing properties of ScCrMn alloy.Journal of Alloys and Compounds,511(1),169-175. |
| MLA | W. H. Li,et al."Structure and hydrogen absorbing properties of ScCrMn alloy".Journal of Alloys and Compounds 511.1(2012):169-175. |
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