Influences of the main anodic electroplating parameters on cerium oxide films

IMR OpenIR

	Influences of the main anodic electroplating parameters on cerium oxide films
	Y. Yang; Y. M. Yang; X. Q. Du; Y. Chen; Z. Zhang; J. Q. Zhang
	2014
发表期刊	Applied Surface Science
ISSN	0169-4332
卷号	305 页码:330-336
摘要	Cerium oxide thin films were fabricated onto 316 L stainless steel via a potentiostatically anodic electrodeposition approach in the solutions containing cerium(III) nitrate (0.05 M), ammonia acetate (0.1 M) and ethanol (10% V/V). The electrochemical behaviors and deposition parameters (applied potential, bath temperature, dissolving 02 and bath pH) have been investigated. Results show that, the electrochemical oxidation of Ce3+ goes through one electrochemical step, which is under charge transfer control. The optimum applied potential for film deposition is 0.8 V. Bath temperature plays a significant effect on the deposition rate, composition (different colors of the film) and surface morphology of the deposits. Due to the hydrolysis of Ce3+, cerous hydroxide is facility to form when the bath temperature is higher than 60 C. The electroplating bath pH is another key role for the anodic deposition of cerium oxide thin films, and the best bath pH is around 6.20. N-2 or O-2 purged into the bath will result in film porosities and O-2 favors cerium oxide particles and film generation. (c) 2014 Elsevier B.V. All rights reserved.
部门归属	[yang, yang ; yang, yumeng ; du, xiaoqing ; chen, yu ; zhang, zhao ; zhang, jianqing] zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. [zhang, jianqing] state key lab corros & protect met, shenyang 110016, peoples r china. ; zhang, z (reprint author), zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. ; eaglezzy@zjuem.zju.edu.cn
关键词	Cerium Oxides Thin Films Anodic Electrodeposition Thin-films Cathodic Electrodeposition Hydrothermal Synthesis Galvanized Steel Silane Films Doped Ceria Ceo2 Powders Nanoparticles Deposition
URL	查看原文
语种	英语
WOS记录号	WOS:000336525400045
引用统计	被引频次：21[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/72954
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Yang,Y. M. Yang,X. Q. Du,et al. Influences of the main anodic electroplating parameters on cerium oxide films[J]. Applied Surface Science,2014,305:330-336.
APA	Y. Yang,Y. M. Yang,X. Q. Du,Y. Chen,Z. Zhang,&J. Q. Zhang.(2014).Influences of the main anodic electroplating parameters on cerium oxide films.Applied Surface Science,305,330-336.
MLA	Y. Yang,et al."Influences of the main anodic electroplating parameters on cerium oxide films".Applied Surface Science 305(2014):330-336.