Unusual phenomena in the reduction process of vanadium(V) on a graphite electrode at high overpotentials

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	Unusual phenomena in the reduction process of vanadium(V) on a graphite electrode at high overpotentials
	W. J. Wang; X. Z. Fan; J. G. Liu; C. W. Yan; C. L. Zeng
	2014
发表期刊	Physical Chemistry Chemical Physics
ISSN	1463-9076
卷号	16 期号:37 页码:19848-19851
摘要	An abrupt increase in the Tafel slope and the charge transfer resistance (R-ct) of V(V) ions on a graphite electrode are both observed at a transition potential (E-K). The possible vanadium complexes such as V2O33+ might result in the change of reduction mechanism and the unusual phenomena.
部门归属	[wang, wenjun ; fan, xinzhuang ; liu, jianguo ; yan, chuanwei ; zeng, chaoliu] chinese acad sci, inst met res, shenyang 110016, peoples r china. ; fan, xz (reprint author), chinese acad sci, inst met res, 62 wencui rd, shenyang 110016, peoples r china. ; xzfan@imr.ac.cn
关键词	Acidic-solutions Redox Battery Flow Battery Solid-state Ions v(Iv)/v(v) Complexes Mechanism Storage Vo2++
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/73424
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. J. Wang,X. Z. Fan,J. G. Liu,et al. Unusual phenomena in the reduction process of vanadium(V) on a graphite electrode at high overpotentials[J]. Physical Chemistry Chemical Physics,2014,16(37):19848-19851.
APA	W. J. Wang,X. Z. Fan,J. G. Liu,C. W. Yan,&C. L. Zeng.(2014).Unusual phenomena in the reduction process of vanadium(V) on a graphite electrode at high overpotentials.Physical Chemistry Chemical Physics,16(37),19848-19851.
MLA	W. J. Wang,et al."Unusual phenomena in the reduction process of vanadium(V) on a graphite electrode at high overpotentials".Physical Chemistry Chemical Physics 16.37(2014):19848-19851.