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Effect of molybdenum, manganese and tungsten contents on the corrosion behavior and hardness of iron-based metallic glasses
Y. Wang; S. L. Jiang; Y. G. Zheng; W. Ke; W. H. Sun; J. Q. Wang
2014
发表期刊Materials and Corrosion-Werkstoffe Und Korrosion
ISSN0947-5117
卷号65期号:7页码:733-741
摘要The effects of molybdenum (Mo), manganese (Mn) and tungsten (W) on the corrosion behavior and hardness of iron-based metallic glasses (MG) were investigated by using electrochemical measurements, X-ray photoelectron spectroscopy, and micro-hardness tester. The results showed that the alloying elements (Mo, Mn, and W) have great influence on the corrosion behavior and hardness. Corrosion resistance of the MG increased with Mo and W content to a critical value (9.4 and 3.2 at%, respectively) and then decreased, while kept increasing with Mn. The corrosion behavior is dependent on the composition of the passive film. The protective Mo(IV), Mn(IV), and W(VI) oxide film on the surface attributes to the enhanced stability of the film. The hardness of the MG is not sensitive to the Mn content, but increased with the Mo and W content. Little influence on the hardness is found when the Mo content is higher than 9.4 at%. Based on the above mentioned influence of alloying elements, corrosion, and wear resistance can be balanced to meet the service of marine pump that served in both corrosive and erosive environments.
部门归属[wang, y. ; jiang, s. l. ; zheng, y. g. ; ke, w.] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [wang, y.] northeast petr univ, dept mat sci & engn, daqing 163318, peoples r china. [sun, w. h. ; wang, j. q.] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. ; zheng, yg (reprint author), chinese acad sci, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110016, peoples r china. ; ygzheng@imr.ac.cn ; jqwang@imr.ac.cn
关键词P-c Alloys Austenitic Stainless-steels 1 m Hcl Passive Film Chloride Solutions Pitting Corrosion Hydrochloric-acid Anodic Behavior Bipolar Model Air Exposure
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/73430
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
Y. Wang,S. L. Jiang,Y. G. Zheng,et al. Effect of molybdenum, manganese and tungsten contents on the corrosion behavior and hardness of iron-based metallic glasses[J]. Materials and Corrosion-Werkstoffe Und Korrosion,2014,65(7):733-741.
APA Y. Wang,S. L. Jiang,Y. G. Zheng,W. Ke,W. H. Sun,&J. Q. Wang.(2014).Effect of molybdenum, manganese and tungsten contents on the corrosion behavior and hardness of iron-based metallic glasses.Materials and Corrosion-Werkstoffe Und Korrosion,65(7),733-741.
MLA Y. Wang,et al."Effect of molybdenum, manganese and tungsten contents on the corrosion behavior and hardness of iron-based metallic glasses".Materials and Corrosion-Werkstoffe Und Korrosion 65.7(2014):733-741.
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