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Effects of the oxidants H2O and CrF3 on the corrosion of pure metals in molten (Li,Na,K)F
Wang, Yan Li; Wang, Qian; Liu, Hui Jun; Zeng, Chao Liu; liuhj@imr.ac.cn
2016
发表期刊CORROSION SCIENCE
ISSN0010-938X
卷号103页码:268-282
摘要The effects of two oxidizing species, H2O and CrF3, on the corrosion of pure metals Ni, Fe and Cr in molten (Li,Na,K)F at 700 degrees C were investigated by potentiodynamic polarization and electrochemical impedance spectroscopy. The results indicated that Ni, Fe and Cr were all in active dissolution state at the corrosion potential and the corrosion current densities were significantly increased when 2% H2O was introduced. However, the addition of CrF3 only accelerated the dissolution of Cr and Fe. Based on the impedance results, the diffusion coefficient of Cr3+ in the melt has been calculated to be 6.25 x 10(-4) cm(2) s(-1) 2015 Elsevier Ltd. All rights reserved.
部门归属[wang, yan li ; wang, qian ; liu, hui jun ; zeng, chao liu] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china
关键词Ni Fe Cr Molten (Li,Na.k)f Corrosion
资助者National Natural Science Foundation of China [51271190, 51501205]
收录类别sci
语种英语
WOS记录号WOS:000369201100028
引用统计
被引频次:90[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/74797
专题中国科学院金属研究所
通讯作者liuhj@imr.ac.cn
推荐引用方式
GB/T 7714
Wang, Yan Li,Wang, Qian,Liu, Hui Jun,et al. Effects of the oxidants H2O and CrF3 on the corrosion of pure metals in molten (Li,Na,K)F[J]. CORROSION SCIENCE,2016,103:268-282.
APA Wang, Yan Li,Wang, Qian,Liu, Hui Jun,Zeng, Chao Liu,&liuhj@imr.ac.cn.(2016).Effects of the oxidants H2O and CrF3 on the corrosion of pure metals in molten (Li,Na,K)F.CORROSION SCIENCE,103,268-282.
MLA Wang, Yan Li,et al."Effects of the oxidants H2O and CrF3 on the corrosion of pure metals in molten (Li,Na,K)F".CORROSION SCIENCE 103(2016):268-282.
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