| Oxygen breaks into carbon nanotubes and abstracts hydrogen from propane | |
| Huang, Rui; Xu, Junyuan; Wang, Jia; Sun, Xiaoyan; Qi, Wei; Liang, Changhai; Su, Dang Sheng; dssu@imr.ac.cn | |
| 2016 | |
| Source Publication | CARBON
 |
| ISSN | 0008-6223 |
| Volume | 96Pages:631-640 |
| Abstract | We have revealed that molecular oxygen breaks into carbon nanotubes forming active sites to abstract hydrogen from propane. Various carbonaceous species (carbon defects and debris) on carbon nanotubes were identified and their effects on the oxo-functionalization as well as the catalytic performance in the oxidative dehydrogenation of propane were thoroughly investigated. The results indicate that certain amount of accessible skeleton defects is beneficial to the selective introduction of ether and ketonic carbonyl groups. However, amorphous carbons are poorly selective during oxo-functionalization and the related functionalities decompose easily during the long-term catalytic test. The proportion of ether and ketonic carbonyl groups obtained from oxygen functionalization reaches to 93%, which is twice more than that obtained from acidic solution treatment. Turnover frequency of 1.5 h(-1) in the oxidative dehydrogenation of propane is successfully correlated with ketonic carbonyl groups (C=O), while there is no obvious correlation between the activity and the amount of ether groups (C-O-C). (C) 2015 Elsevier Ltd. All rights reserved. |
| description.department | [huang, rui ; xu, junyuan ; wang, jia ; sun, xiaoyan ; qi, wei ; su, dang sheng] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china ; [huang, rui ; liang, changhai] dalian univ technol, lab adv mat & catalyt engn, dalian 116024, peoples r china |
| Funding Organization | MOST [2011CBA00504]; NSFC of China [21133010, 21203215, 51221264, 21261160487]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103] |
| Indexed By | sci |
| Language | 英语 |
| WOS ID | WOS:000366078000075 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/75049 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | dssu@imr.ac.cn |
| Recommended Citation GB/T 7714 | Huang, Rui,Xu, Junyuan,Wang, Jia,et al. Oxygen breaks into carbon nanotubes and abstracts hydrogen from propane[J]. CARBON,2016,96:631-640. |
| APA | Huang, Rui.,Xu, Junyuan.,Wang, Jia.,Sun, Xiaoyan.,Qi, Wei.,...&dssu@imr.ac.cn.(2016).Oxygen breaks into carbon nanotubes and abstracts hydrogen from propane.CARBON,96,631-640. |
| MLA | Huang, Rui,et al."Oxygen breaks into carbon nanotubes and abstracts hydrogen from propane".CARBON 96(2016):631-640. |
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