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Preparation and electrochemical performance of ZrO2 nanoparticle-embedded nonwoven composite separator for lithium-ion batteries
Xiao, Wei; Gong, Yaqun; Wang, Hong; Zhao, Lina; Liu, Jianguo; Yan, Chuanwei; wxiao@imr.ac.cn
2015
发表期刊CERAMICS INTERNATIONAL
ISSN0272-8842
卷号41期号:10页码:14223-14229
摘要To improve the safety of lithium-ion batteries, a high performance composite separator based on ZrO2 nanoparticles and poly (ethylene terephthalate) nonwoven was successfully prepared. Systematical investigations including morphology characterization, porosity measurement, electrolyte wettability, thermal shrinkage testing, and cell performance examination were carried out. The results show that ZrO2 nanoparticles and nonwoven substrate endow the composite separator with outstanding thermostability, which may lead to improved safety of the batteries. Meanwhile, the composite separator possesses unique porous structure formed between ZrO2 particles. Owing to the relatively polar constituents and well-developed microstructure, the composite separator exhibits higher air permeability and porosity, as well as superior electrolyte wettability compared to the commercialized polyethylene separator. Based on the above advantages, this composite separator shows better electrochemical properties, such as the discharge C-rate capability and cycling performance, as compared to the polyethylene separator. This research presents a simple approach to prepare high performance separator, which is demonstrated to be a good candidate for lithium-ion batteries. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
部门归属[xiao, wei ; gong, yaqun ; wang, hong ; zhao, lina ; liu, jianguo ; yan, chuanwei] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china
关键词Lithium-ion Battery Separator Inorganic Particles Electrolyte Wettability Thermal Stability
资助者National Natural Science Foundation of China [21306213]
收录类别sci
语种英语
WOS记录号WOS:000362919900036
引用统计
被引频次:41[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/75069
专题中国科学院金属研究所
通讯作者wxiao@imr.ac.cn
推荐引用方式
GB/T 7714
Xiao, Wei,Gong, Yaqun,Wang, Hong,et al. Preparation and electrochemical performance of ZrO2 nanoparticle-embedded nonwoven composite separator for lithium-ion batteries[J]. CERAMICS INTERNATIONAL,2015,41(10):14223-14229.
APA Xiao, Wei.,Gong, Yaqun.,Wang, Hong.,Zhao, Lina.,Liu, Jianguo.,...&wxiao@imr.ac.cn.(2015).Preparation and electrochemical performance of ZrO2 nanoparticle-embedded nonwoven composite separator for lithium-ion batteries.CERAMICS INTERNATIONAL,41(10),14223-14229.
MLA Xiao, Wei,et al."Preparation and electrochemical performance of ZrO2 nanoparticle-embedded nonwoven composite separator for lithium-ion batteries".CERAMICS INTERNATIONAL 41.10(2015):14223-14229.
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