The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction

IMR OpenIR

	The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction
	Sun, Xiaoyan; Xu, Junyuan; Ding, Yuxiao; Zhang, Bingsen; Feng, Zhenbao; Su, Dang Sheng; dssu@imr.ac.cn
	2015
发表期刊	CHEMSUSCHEM
ISSN	1864-5631
卷号	8 期号:17 页码:2872-2876
摘要	Two kinds of phosphorus-modified onion-like carbons dominated by C-O-P bonds and C-P bonds were fabricated and further used as catalysts in the oxygen reduction reaction (ORR). The results show that the bonding state of phosphorus has a significant effect on the ORR catalytic activity. The formation of C-O-P bonds improves ORR activity, whereas C-P bonds play an adverse role in stabilizing the key intermediates during the ORR owing to the distorted graphitic structure, as confirmed by the work function value.
部门归属	[sun, xiaoyan ; xu, junyuan ; ding, yuxiao ; zhang, bingsen ; feng, zhenbao ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china
关键词	Doping Electrocatalysis Onion-like Carbon Oxygen Reduction Phosphorus
资助者	Ministry of Science and Technology (MOST) [2011CBA00504]; National Natural Science Foundation of China (NSFC) [21133010, 21103203, 51221264, 21261160487, 21203215]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103]
收录类别	sci
语种	英语
WOS记录号	WOS:000360915800009
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75188
专题	中国科学院金属研究所
通讯作者	dssu@imr.ac.cn
推荐引用方式 GB/T 7714	Sun, Xiaoyan,Xu, Junyuan,Ding, Yuxiao,et al. The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction[J]. CHEMSUSCHEM,2015,8(17):2872-2876.
APA	Sun, Xiaoyan.,Xu, Junyuan.,Ding, Yuxiao.,Zhang, Bingsen.,Feng, Zhenbao.,...&dssu@imr.ac.cn.(2015).The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction.CHEMSUSCHEM,8(17),2872-2876.
MLA	Sun, Xiaoyan,et al."The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction".CHEMSUSCHEM 8.17(2015):2872-2876.