The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity

IMR OpenIR

	The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity
	Sun, XiaoYing; Li, Bo; Su, DangSheng; Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
	2016-06-06
发表期刊	CHEMISTRY-AN ASIAN JOURNAL
ISSN	1861-4728
卷号	11 期号:11 页码:1668-1671
摘要	It is believed that the oxygen groups on the carbon catalysts are responsible for the observed reactivity for C-H bond activations. On the other hand, the oxygen groups also reduce the aromaticity of the host. The loss of the aromaticity increases reactivities of the carbon atoms and they become the active sites for the C-H bond activation. The newly identified C-C site exhibits the comparable catalytic performance in the oxidative dehydrogenation (ODH) of propane compared with the conventional oxygen groups like quinone and ketone. A series of calculations indicate that the aromaticity might be a useful descriptor for the carbon catalysts.
部门归属	[sun, xiaoying] shenyang normal univ, inst catalysis energy & environm, shenyang 110034, peoples r china ; [li, bo ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china
关键词	Aromaticity Carbon Catalyst Dehydrogenation Heterogeneous Catalysis Nanocatalysis
学科领域	Chemistry
资助者	NSFC of China [21573255, 21133010, 51221264]; Chinese Academy of Sciences [XDA09030103]; Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund; Institute of Metal Research [Y3NBA211A1]
收录类别	sci
语种	英语
WOS记录号	WOS:000379519100004
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75835
专题	中国科学院金属研究所
通讯作者	Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
推荐引用方式 GB/T 7714	Sun, XiaoYing,Li, Bo,Su, DangSheng,et al. The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(11):1668-1671.
APA	Sun, XiaoYing,Li, Bo,Su, DangSheng,Li, B,&Su, DS .(2016).The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity.CHEMISTRY-AN ASIAN JOURNAL,11(11),1668-1671.
MLA	Sun, XiaoYing,et al."The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity".CHEMISTRY-AN ASIAN JOURNAL 11.11(2016):1668-1671.