The Combination Addition of 2-Mercapto-5-benzimidazolesulfonic Acid and Thiourea to Watts Bath in Controllable Electro-Healing Cracks in Nickel | |
Zheng, X. G.; Shi, Y. -N.; Lu, K.; Shi, YN (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China. | |
2016 | |
发表期刊 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
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ISSN | 0013-4651 |
卷号 | 163期号:8页码:D349-D354 |
摘要 | Based upon previous investigations on crack electro-healing by the addition of only inhibitor(s), the present paper concentrates on the exploration of the crack electro-healing behavior in pure Ni with the combination presence of an inhibitor 2-Mercapto-5-benzimidazolesulfonic acid (MBIS) and an accelerator thiourea (TU) in Watts bath. Voltammetry was performed to characterize the electrochemical aspect when these two additives were added. Current transient and injection experiments were conducted to study the synergistic effect of MBIS and TU to Ni deposition. It is proposed that TU will displace some of the MBIS molecules adsorbed on the electrode surface, which will break up the blocking layer of MBIS, therefore avoid the formation of annual-ring-like defects that form when only MBIS is present. (C) 2016 The Electrochemical Society. All rights reserved. |
部门归属 | [zheng, x. g. ; shi, y. -n. ; lu, k.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china |
学科领域 | Electrochemistry ; Materials Science |
资助者 | Ministry of Science & Technology of China [2012CB932201]; National Science Foundation of China [51231006]; International Cooperation Program - National Science Foundation of China [51261130091]; Key Research Program of Chinese Academy of Sciences [KGZD-EW-T06] |
收录类别 | sci |
语种 | 英语 |
WOS记录号 | WOS:000379688000069 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/75949 |
专题 | 中国科学院金属研究所 |
通讯作者 | Shi, YN (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China. |
推荐引用方式 GB/T 7714 | Zheng, X. G.,Shi, Y. -N.,Lu, K.,et al. The Combination Addition of 2-Mercapto-5-benzimidazolesulfonic Acid and Thiourea to Watts Bath in Controllable Electro-Healing Cracks in Nickel[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2016,163(8):D349-D354. |
APA | Zheng, X. G.,Shi, Y. -N.,Lu, K.,&Shi, YN .(2016).The Combination Addition of 2-Mercapto-5-benzimidazolesulfonic Acid and Thiourea to Watts Bath in Controllable Electro-Healing Cracks in Nickel.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,163(8),D349-D354. |
MLA | Zheng, X. G.,et al."The Combination Addition of 2-Mercapto-5-benzimidazolesulfonic Acid and Thiourea to Watts Bath in Controllable Electro-Healing Cracks in Nickel".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 163.8(2016):D349-D354. |
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