The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments

IMR OpenIR

	The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments
	Qian, Hongchang; Zhang, Dawei; Deng, Leping; Huang, Luyao; Xu, Dake; Du, Cuiwei; Li, Xiaogang; Zhang, DW; Xu, DK (reprint author), Univ Sci & Technol Beijing, Ctr Corros & Protect, Beijing 100083, Peoples R China.
	2017-03-01
发表期刊	PROGRESS IN ORGANIC COATINGS
ISSN	0300-9440
卷号	104 页码:199-209
摘要	Hydrophobic epoxy coatings with particulated surfaces were prepared via soft lithography using different abrasive papers as the templates. With the increasing surface roughness, the hydrophobicity of these surfaces first increased and then decreased and a maximum water contact angle of similar to 136 degrees was obtained by using a P2000 abrasive paper as the template. Electrochemical impedance spectroscopy (EIS) was used to study the role of surface morphology in the coatings' barrier properties under wet-dry cyclic immersion and in salt-spray environments. The results demonstrated that the hydrophobicity induced by the trapped air in the surface microstructures produced stronger-barrier properties than that produced by a smooth coating when exposed to wet-dry cyclic immersion. The strongest barrier performance was achieved by the coating templated with the P2000 abrasive paper, However, these microstructured hydrophobic coatings deteriorated faster in the salt-spray tests because of the direct deposition of salt electrolyte particles on the coating surfaces and the increased coating surface area. Under the salt spray condition, the coating obtained from P6000 abrasive paper exhibited the fastest deterioration. (C) 2016 Elsevier B.V. All rights reserved.; Hydrophobic epoxy coatings with particulated surfaces were prepared via soft lithography using different abrasive papers as the templates. With the increasing surface roughness, the hydrophobicity of these surfaces first increased and then decreased and a maximum water contact angle of similar to 136 degrees was obtained by using a P2000 abrasive paper as the template. Electrochemical impedance spectroscopy (EIS) was used to study the role of surface morphology in the coatings' barrier properties under wet-dry cyclic immersion and in salt-spray environments. The results demonstrated that the hydrophobicity induced by the trapped air in the surface microstructures produced stronger-barrier properties than that produced by a smooth coating when exposed to wet-dry cyclic immersion. The strongest barrier performance was achieved by the coating templated with the P2000 abrasive paper, However, these microstructured hydrophobic coatings deteriorated faster in the salt-spray tests because of the direct deposition of salt electrolyte particles on the coating surfaces and the increased coating surface area. Under the salt spray condition, the coating obtained from P6000 abrasive paper exhibited the fastest deterioration. (C) 2016 Elsevier B.V. All rights reserved.
部门归属	[qian, hongchang ; zhang, dawei ; deng, leping ; huang, luyao ; xu, dake ; du, cuiwei ; li, xiaogang] univ sci & technol beijing, ctr corros & protect, beijing 100083, peoples r china ; [xu, dake] chinese acad sci, inst met res, shenyang 110016, peoples r china
关键词	Organic Coatings Corrosion Eis Hydrophobicity Interfaces
学科领域	Chemistry, Applied ; Materials Science, Coatings & Films
资助者	National Natural Science Foundation of China [51401018]; Fundamental Research Funds for the Central Universities [FRF-TP-15-054A2]; National Basic Research Program of China (973 Program) [2014CB643300]; Open Fund of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences [MCKF201609]
收录类别	SCI
语种	英语
WOS记录号	WOS:000394074400025
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/78266
专题	中国科学院金属研究所
通讯作者	Zhang, DW; Xu, DK (reprint author), Univ Sci & Technol Beijing, Ctr Corros & Protect, Beijing 100083, Peoples R China.
推荐引用方式 GB/T 7714	Qian, Hongchang,Zhang, Dawei,Deng, Leping,et al. The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments[J]. PROGRESS IN ORGANIC COATINGS,2017,104:199-209.
APA	Qian, Hongchang.,Zhang, Dawei.,Deng, Leping.,Huang, Luyao.,Xu, Dake.,...&Xu, DK .(2017).The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments.PROGRESS IN ORGANIC COATINGS,104,199-209.
MLA	Qian, Hongchang,et al."The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments".PROGRESS IN ORGANIC COATINGS 104(2017):199-209.