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Highly Conductive Transition Metal Carbide/Carbonitride(MXene)@polystyrene Nanocomposites Fabricated by Electrostatic Assembly for Highly Efficient Electromagnetic Interference Shielding
Sun, Renhui; Zhang, Hao-Bin; Liu, Ji; Xie, Xi; Yang, Rui; Li, Yue; Hong, Song; Yu, Zhong-Zhen; Zhang, HB; Yu, ZZ (reprint author), Beijing Univ Chem Technol, Coll Mat Sci & Engn, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China.
2017-12-01
发表期刊WILEY-V C H VERLAG GMBH
ISSN1616-301X
卷号27期号:45页码:-
摘要Highly conductive polymer nanocomposites are greatly desired for electromagnetic interference (EMI) shielding applications. Although transition metal carbide/carbonitride (MXene) has shown its huge potential for producing highly conductive films and bulk materials, it still remains a great challenge to fabricate extremely conductive polymer nanocomposites with outstanding EMI shielding performance at minimal amounts of MXenes. Herein, an electrostatic assembly approach for fabricating highly conductive MXene@polystyrene nanocomposites by electrostatic assembling of negative MXene nanosheets on positive polystyrene microspheres is demonstrated, followed by compression molding. Thanks to the high conductivity of MXenes and their highly efficient conducting network within polystyrene matrix, the resultant nanocomposites exhibit not only a low percolation threshold of 0.26 vol% but also a superb conductivity of 1081 S m(-1) and an outstanding EMI shielding performance of >54 dB over the whole X-band with a maximum of 62 dB at the low MXene loading of 1.90 vol%, which are among the best performances for electrically conductive polymer nanocomposites by far. Moreover, the same nanocomposite has a highly enhanced storage modulus, 54% and 56% higher than those of neat polystyrene and conventional MXene@polystyrene nanocomposite, respectively. This work provides a novel methodology to produce highly conductive polymer nanocomposites for highly efficient EMI shielding applications.; Highly conductive polymer nanocomposites are greatly desired for electromagnetic interference (EMI) shielding applications. Although transition metal carbide/carbonitride (MXene) has shown its huge potential for producing highly conductive films and bulk materials, it still remains a great challenge to fabricate extremely conductive polymer nanocomposites with outstanding EMI shielding performance at minimal amounts of MXenes. Herein, an electrostatic assembly approach for fabricating highly conductive MXene@polystyrene nanocomposites by electrostatic assembling of negative MXene nanosheets on positive polystyrene microspheres is demonstrated, followed by compression molding. Thanks to the high conductivity of MXenes and their highly efficient conducting network within polystyrene matrix, the resultant nanocomposites exhibit not only a low percolation threshold of 0.26 vol% but also a superb conductivity of 1081 S m(-1) and an outstanding EMI shielding performance of >54 dB over the whole X-band with a maximum of 62 dB at the low MXene loading of 1.90 vol%, which are among the best performances for electrically conductive polymer nanocomposites by far. Moreover, the same nanocomposite has a highly enhanced storage modulus, 54% and 56% higher than those of neat polystyrene and conventional MXene@polystyrene nanocomposite, respectively. This work provides a novel methodology to produce highly conductive polymer nanocomposites for highly efficient EMI shielding applications.
部门归属[sun, renhui ; zhang, hao-bin ; liu, ji ; yu, zhong-zhen] beijing univ chem technol, coll mat sci & engn, state key lab organ inorgan composites, beijing 100029, peoples r china ; [sun, renhui] handan purificat equipment res inst, handan 056027, peoples r china ; [xie, xi ; yang, rui] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china ; [hong, song] beijing univ chem technol, anal & test ctr, beijing 100029, peoples r china
关键词Electromagnetic Interference Shielding Electrical Conductivity Mxene Nanocomposites Polystyrene
学科领域Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
资助者National Natural Science Foundation of China [51673015, 51373011, 51533001]; Fundamental Research Funds for the Central Universities [YS201402]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/78949
专题中国科学院金属研究所
通讯作者Zhang, HB; Yu, ZZ (reprint author), Beijing Univ Chem Technol, Coll Mat Sci & Engn, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China.
推荐引用方式
GB/T 7714
Sun, Renhui,Zhang, Hao-Bin,Liu, Ji,et al. Highly Conductive Transition Metal Carbide/Carbonitride(MXene)@polystyrene Nanocomposites Fabricated by Electrostatic Assembly for Highly Efficient Electromagnetic Interference Shielding[J]. WILEY-V C H VERLAG GMBH,2017,27(45):-.
APA Sun, Renhui.,Zhang, Hao-Bin.,Liu, Ji.,Xie, Xi.,Yang, Rui.,...&Yu, ZZ .(2017).Highly Conductive Transition Metal Carbide/Carbonitride(MXene)@polystyrene Nanocomposites Fabricated by Electrostatic Assembly for Highly Efficient Electromagnetic Interference Shielding.WILEY-V C H VERLAG GMBH,27(45),-.
MLA Sun, Renhui,et al."Highly Conductive Transition Metal Carbide/Carbonitride(MXene)@polystyrene Nanocomposites Fabricated by Electrostatic Assembly for Highly Efficient Electromagnetic Interference Shielding".WILEY-V C H VERLAG GMBH 27.45(2017):-.
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