Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes

IMR OpenIR

	Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes
	Gupta, Neeraj; Khavryuchenko, Oleksiy; Villa, Alberto; Su, Dangsheng; Su, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China.
	2017-08-10
发表期刊	WILEY-V C H VERLAG GMBH
ISSN	1864-5631
卷号	10 期号:15 页码:3030-3034
摘要	Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.; Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.
部门归属	[gupta, neeraj ; su, dangsheng] chinese acad sci, catalysis div, imr shenyang natl lab, shenyang 110016, liaoning, peoples r china ; [khavryuchenko, oleksiy] tmm llc, res & dev dept, volodymyrska str 49a, kiev, ukraine ; [villa, alberto] univ milan, dipartimento chim, via golgi 19, i-20133 milan, italy ; [su, dangsheng] chinese acad sci, dalian inst chem phys, dalian, peoples r china
关键词	Biomass Conversion Carbon Nanotubes Glycerol Metal-free Oxidation Ncnts
学科领域	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
资助者	Chinese Academy of Sciences [2014FFGB0006]; Universita degli Studi di Milano, "Piano di sviluppo d'ateneo, Linea 2 Azione A"
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79153
专题	中国科学院金属研究所
通讯作者	Su, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China.
推荐引用方式 GB/T 7714	Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,et al. Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes[J]. WILEY-V C H VERLAG GMBH,2017,10(15):3030-3034.
APA	Gupta, Neeraj.,Khavryuchenko, Oleksiy.,Villa, Alberto.,Su, Dangsheng.,Su, DS .,...&Su, DS .(2017).Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes.WILEY-V C H VERLAG GMBH,10(15),3030-3034.
MLA	Gupta, Neeraj,et al."Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes".WILEY-V C H VERLAG GMBH 10.15(2017):3030-3034.