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Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution
Li, YZ; Niu, SQ; Rakov, D; Wang, Y; Caban-Acevedo, M; Zheng, SJ; Song, B; Xu, P; Xu, P (reprint author), Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China.; Song, B (reprint author), Harbin Inst Technol, Dept Phys, Acad Fundamental & Interdisciplinary Sci, Harbin 150001, Heilongjiang, Peoples R China.
2018-04-21
发表期刊NANOSCALE
ISSN2040-3364
卷号10期号:15页码:7291-7297
摘要Electrocatalytic hydrogen evolution has attracted a great deal of attention due to the urgent need for clean energy. Herein, we demonstrate the synthesis of ternary pyrite-type cobalt phosphosulphide (CoPS) nanoparticles supported on a nitrogen-doped carbon matrix, CoPS/N-C, through carbonization and subsequent phosphosulfurization of Co-based zeolitic imidazolate frameworks (ZIF-67), as promising hydrogen evolution reaction (HER) electrocatalysts in both acidic and alkaline solutions. The polyhedral structure of ZIF-67 can be well maintained in the as-prepared CoPS/N-C nanocomposites. In particular, CoPS/N-C provides a geometric catalytic current density of -10 mA cm(-2) at overpotentials of -80 and -148 mV vs. a reversible hydrogen electrode (RHE) and a Tafel slope of 68 and 78 mV dec(-1) in 0.5 M H2SO4 and 1 M KOH, respectively, which is superior to most of the transition metal phosphosulfide materials. This MOF-derived synthesis of a transition metal phosphosulfide supported heteroatom-doped carbon matrix provides a promising opportunity for the development of highly efficient electrocatalysts for renewable energy devices.; Electrocatalytic hydrogen evolution has attracted a great deal of attention due to the urgent need for clean energy. Herein, we demonstrate the synthesis of ternary pyrite-type cobalt phosphosulphide (CoPS) nanoparticles supported on a nitrogen-doped carbon matrix, CoPS/N-C, through carbonization and subsequent phosphosulfurization of Co-based zeolitic imidazolate frameworks (ZIF-67), as promising hydrogen evolution reaction (HER) electrocatalysts in both acidic and alkaline solutions. The polyhedral structure of ZIF-67 can be well maintained in the as-prepared CoPS/N-C nanocomposites. In particular, CoPS/N-C provides a geometric catalytic current density of -10 mA cm(-2) at overpotentials of -80 and -148 mV vs. a reversible hydrogen electrode (RHE) and a Tafel slope of 68 and 78 mV dec(-1) in 0.5 M H2SO4 and 1 M KOH, respectively, which is superior to most of the transition metal phosphosulfide materials. This MOF-derived synthesis of a transition metal phosphosulfide supported heteroatom-doped carbon matrix provides a promising opportunity for the development of highly efficient electrocatalysts for renewable energy devices.
部门归属[li, yuzhi ; niu, siqi ; rakov, dmitrii ; wang, ying ; xu, ping] harbin inst technol, sch chem & chem engn, miit key lab crit mat technol new energy convers, harbin 150001, heilongjiang, peoples r china ; [caban-acevedo, miguel] univ wisconsin, dept chem, 1101 univ ave, madison, wi 53706 usa ; [zheng, shijian] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, liaoning, peoples r china ; [song, bo] harbin inst technol, dept phys, acad fundamental & interdisciplinary sci, harbin 150001, heilongjiang, peoples r china
关键词Wide Ph Range Oxygen Evolution Bifunctional Electrocatalysts Molybdenum-disulfide Water Graphene Nanoparticles Catalyst Nitrogen Phosphosulfide
学科领域Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
资助者Fundamental Research Funds for the Central Universities [A201502, 201223]; Postdoctoral Scientific Research Fund of Heilongjiang Province [LBH-Q14062, LBH-Z14076]; International Science & Technology Cooperation Program of China [2012DFR50020]; National Natural Science Foundation of China [51472064, 21471039, 51372056, 21671047, 51672057]; China Postdoctoral Science Foundation [2014M560253]; Program for New Century Excellent Talents in University [NCET-13-0174]; Natural Science Foundation of Heilongjiang Province [B2015001]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/79358
专题中国科学院金属研究所
通讯作者Xu, P (reprint author), Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China.; Song, B (reprint author), Harbin Inst Technol, Dept Phys, Acad Fundamental & Interdisciplinary Sci, Harbin 150001, Heilongjiang, Peoples R China.
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Li, YZ,Niu, SQ,Rakov, D,et al. Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution[J]. NANOSCALE,2018,10(15):7291-7297.
APA Li, YZ.,Niu, SQ.,Rakov, D.,Wang, Y.,Caban-Acevedo, M.,...&Song, B .(2018).Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution.NANOSCALE,10(15),7291-7297.
MLA Li, YZ,et al."Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution".NANOSCALE 10.15(2018):7291-7297.
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