Knowledge Management System Of Institute of metal research，CAS
| Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism | |
| Gupta, N; Khavryuchenko, O; Wen, GD; Wu, KH; Su, DS; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. | |
| 2018-04-01 | |
| Source Publication | CARBON
 |
| ISSN | 0008-6223 |
| Volume | 130Pages:714-723 |
| Abstract | Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved.; Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved. |
| description.department | [gupta, neeraj ; wen, guodong ; wu, kuang-hsu ; su, dangsheng] chinese acad sci, inst met res, 72 wenhua rd, shenyang 110016, liaoning, peoples r china ; [gupta, neeraj] shoolini univ, sch chem, fac basic sci, solan 173229, hp, india ; [khavryuchenko, oleksiy] tmm llc, res & dev dept, volodymyrska str 49a, ua-01601 kiev, ukraine ; [khavryuchenko, oleksiy] ctr res mol modeling, montreal, pq h4b 1r6, canada ; [su, dangsheng] chinese acad sci, dalian inst chem phys, dalian, peoples r china |
| Keyword | Metal-free Catalyst Carbon Nanotubes Oxidative Dehydrogenation Graphene Oxide Hydrazine Efficient Nanodiamonds Exchange Glycerol Benzene |
| Subject Area | Chemistry, Physical ; Materials Science, Multidisciplinary |
| Funding Organization | Chinese Academy of Sciences [2014FFGB0006]; National Natural Science Foundation of China [21503241, 21473223, 51521091] |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/79413 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
| Recommended Citation GB/T 7714 | Gupta, N,Khavryuchenko, O,Wen, GD,et al. Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism[J]. CARBON,2018,130:714-723. |
| APA | Gupta, N,Khavryuchenko, O,Wen, GD,Wu, KH,Su, DS,&Su, DS .(2018).Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism.CARBON,130,714-723. |
| MLA | Gupta, N,et al."Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism".CARBON 130(2018):714-723. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment