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| A MoS2 nanocatalyst with surface-enriched active sites for the heterogeneous transfer hydrogenation of nitroarenes | |
| Wang, J; Zhang, YJ; Diao, JY; Zhang, JY; Liu, HY; Su, DS; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Energy Res Resources Div, Dalian 116023, Liaoning, Peoples R China. | |
| 2018-01-18 | |
| Source Publication | CHINESE JOURNAL OF CATALYSIS
 |
| ISSN | 1872-2067 |
| Volume | 39Issue:1Pages:79-87 |
| Abstract | A highly efficient and reusable plane-curved and interlayer-expanded MoS2 nanocatalyst with increased exposure of active sites was prepared. The catalyst was used for the heterogeneous hydrogen transfer reaction of nitroarenes with hydrazine monohydrate as a reductant under mild reaction conditions without pressure and base, which was different from other hydrogen transfer systems that require the presence of a base (e.g., propan-2-ol/KOH). The sandwiching of carbon between the MoS2 nanosheets increased the distance between the layers of MoS2 and exposed more Mo sites, resulting in superior catalytic performance compared with that of bulk MoS2 catalyst The active hydrogen (H*) generated from N2H4 could directly transfer to the -NO2 groups of nitrobenzene to form aniline followed by N-2 emission, which was confirmed by detecting the gas emission with mass spectrometry during the decomposition of hydrazine or the co-existence of nitrobenzene and hydrazine. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.; A highly efficient and reusable plane-curved and interlayer-expanded MoS2 nanocatalyst with increased exposure of active sites was prepared. The catalyst was used for the heterogeneous hydrogen transfer reaction of nitroarenes with hydrazine monohydrate as a reductant under mild reaction conditions without pressure and base, which was different from other hydrogen transfer systems that require the presence of a base (e.g., propan-2-ol/KOH). The sandwiching of carbon between the MoS2 nanosheets increased the distance between the layers of MoS2 and exposed more Mo sites, resulting in superior catalytic performance compared with that of bulk MoS2 catalyst The active hydrogen (H*) generated from N2H4 could directly transfer to the -NO2 groups of nitrobenzene to form aniline followed by N-2 emission, which was confirmed by detecting the gas emission with mass spectrometry during the decomposition of hydrazine or the co-existence of nitrobenzene and hydrazine. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| description.department | [wang, jia ; zhang, yajie ; diao, jiangyong ; zhang, jiayun ; liu, hongyang ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, liaoning, peoples r china ; [wang, jia] chinese acad sci, lanzhou inst chem phys, state key lab oxo synth & select oxidat, lanzhou 730000, gansu, peoples r china ; [zhang, yajie ; zhang, jiayun] univ sci & technol china, sch mat sci & engn, shenyang 110016, liaoning, peoples r china ; [su, dangsheng] chinese acad sci, dalian inst chem phys, dalian natl lab clean energy, energy res resources div, dalian 116023, liaoning, peoples r china |
| Keyword | Aromatic Nitro-compounds Transmission Electron-microscopy Molybdenum Sulfide Hydrazine Hydrate Chemoselective Hydrogenation Selective Reduction Catalytic-activity Edge Sites Efficient Hydrodesulfurization |
| Subject Area | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| Funding Organization | Ministry of Science and Technology (MOST) [2016YFA0204100, 2011CBA00504]; National Natural Science Foundation of China [21573254, 91545110]; Youth Innovation Promotion Association (CAS); Sinopec China |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/79573 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, HY; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Energy Res Resources Div, Dalian 116023, Liaoning, Peoples R China. |
| Recommended Citation GB/T 7714 | Wang, J,Zhang, YJ,Diao, JY,et al. A MoS2 nanocatalyst with surface-enriched active sites for the heterogeneous transfer hydrogenation of nitroarenes[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(1):79-87. |
| APA | Wang, J.,Zhang, YJ.,Diao, JY.,Zhang, JY.,Liu, HY.,...&Su, DS .(2018).A MoS2 nanocatalyst with surface-enriched active sites for the heterogeneous transfer hydrogenation of nitroarenes.CHINESE JOURNAL OF CATALYSIS,39(1),79-87. |
| MLA | Wang, J,et al."A MoS2 nanocatalyst with surface-enriched active sites for the heterogeneous transfer hydrogenation of nitroarenes".CHINESE JOURNAL OF CATALYSIS 39.1(2018):79-87. |
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