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Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene
Huang, Fei; Jia, Zhimin; Diao, Jiangyong; Yuan, Hua; Su, Dangsheng; Liu, Hongyang
2019-06-01
Source PublicationJOURNAL OF ENERGY CHEMISTRY
ISSN2095-4956
Volume33Pages:31-36
AbstractWe report a nanocarbon material with nanodiamond (ND) core and graphene shell (ND@G) as a support for Pd nanocatalysts. The designed catalyst performed good selectivity of styrene (85.2%) at full conversion of phenylacetylene and superior stability under mild conditions. Supported Pd catalysts are characterized by means of high resolution transmission electron microscopy (HRTEM), Raman, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and H-2 temperature-programmed reduction (H-2-TPR). The results clearly show that formation of the strong metal-support interaction (SMSI) between Pd nanoclusters and the defective graphene shell helpfully modifies the selectivity and stability of the Pd-based catalysts. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
KeywordSelective hydrogenation Palladium nanoclusters Nanocarbon support Liquid-phase hydrogenation
Indexed BySCI
Language英语
WOS IDWOS:000457881000005
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/81071
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Huang, Fei,Jia, Zhimin,Diao, Jiangyong,et al. Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene[J]. JOURNAL OF ENERGY CHEMISTRY,2019,33:31-36.
APA Huang, Fei,Jia, Zhimin,Diao, Jiangyong,Yuan, Hua,Su, Dangsheng,&Liu, Hongyang.(2019).Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene.JOURNAL OF ENERGY CHEMISTRY,33,31-36.
MLA Huang, Fei,et al."Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene".JOURNAL OF ENERGY CHEMISTRY 33(2019):31-36.
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