Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method | |
Wang, JF; Xiong, R; Yi, F; Yin, D; Ke, MZ; Li, CZ; Liu, ZY; Shi, J | |
通讯作者 | Wang, JF(janson_iris@163.com) |
2005-05-01 | |
发表期刊 | JOURNAL OF SOLID STATE CHEMISTRY
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ISSN | 0022-4596 |
卷号 | 178期号:5页码:1440-1444 |
摘要 | High quality and large-sized Rb0.3MoO3 single crystals were synthesized by molten salt electrolysis method. X-ray diffraction (XRD) patterns and rocking curves, as well as the white beam Laue diffraction of X-ray images show the crystals grown by this method have high quality. The lattice constants evaluated from XRD patterns are a(0) = 1.87 nm, b(0) = 0.75 nm, c(0) = 1.00 nm, β = 118.83(°). The in situ selected area electron diffraction (SAED) patterns along the [10(1) over bar], [1 (11) over bar] and [10(3) over bar] zone axes at room temperature indicate that the Rb0.3MoO3 crystal possess perfect C-centered symmetry. Temperature dependence of the resistivity shows this compound undergoes a metal to semiconductor transition at 183 K. © 2005 Elsevier Inc. All rights reserved. |
关键词 | blue bronze Rb0.3MoO3 single crystal growth electrolytic reduction charge density wave |
DOI | 10.1016/j.jssc.2005.02.015 |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
WOS记录号 | WOS:000228934800012 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/82733 |
通讯作者 | Wang, JF |
作者单位 | 1.Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China 2.Int Ctr Mat Phys, Shenyang 110015, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, JF,Xiong, R,Yi, F,et al. Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method[J]. JOURNAL OF SOLID STATE CHEMISTRY,2005,178(5):1440-1444. |
APA | Wang, JF.,Xiong, R.,Yi, F.,Yin, D.,Ke, MZ.,...&Shi, J.(2005).Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method.JOURNAL OF SOLID STATE CHEMISTRY,178(5),1440-1444. |
MLA | Wang, JF,et al."Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method".JOURNAL OF SOLID STATE CHEMISTRY 178.5(2005):1440-1444. |
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