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EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals
Zheng, WC; Qing, Z; Wu, XX; Yang, M
通讯作者Zheng, WC(zhengwc1@163.com)
2005-04-01
发表期刊SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN1386-1425
卷号61期号:6页码:1243-1246
摘要The calculations of EPR parameters (g factors g(parallel to), g(perpendicular to) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr3+ ions in trigonal KSc(MoO4)(2), RbSc(MoO4)(2) and RbSc(MoO4)(2) crystals. It is found that the MO6 octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. The results are discussed. (c) 2004 Elsevier B.V. All rights reserved.
关键词local lattice distortion electron paramagnetic resonance (EPR) crystal and ligand-field theory Cr3+ KSc(MoO4)(2) RbIn(MoO4)(2) RbSC(MoO4)(2)
DOI10.1016/j.saa.2004.06.047
收录类别SCI
语种英语
WOS研究方向Spectroscopy
WOS类目Spectroscopy
WOS记录号WOS:000227852200032
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/82978
通讯作者Zheng, WC
作者单位1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
2.Flying Inst China, Dept Phys Civil Aviat, Guanghan 618307, Peoples R China
3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
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GB/T 7714
Zheng, WC,Qing, Z,Wu, XX,et al. EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2005,61(6):1243-1246.
APA Zheng, WC,Qing, Z,Wu, XX,&Yang, M.(2005).EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,61(6),1243-1246.
MLA Zheng, WC,et al."EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 61.6(2005):1243-1246.
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