EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals | |
Zheng, WC; Qing, Z; Wu, XX; Yang, M | |
通讯作者 | Zheng, WC(zhengwc1@163.com) |
2005-04-01 | |
发表期刊 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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ISSN | 1386-1425 |
卷号 | 61期号:6页码:1243-1246 |
摘要 | The calculations of EPR parameters (g factors g(parallel to), g(perpendicular to) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr3+ ions in trigonal KSc(MoO4)(2), RbSc(MoO4)(2) and RbSc(MoO4)(2) crystals. It is found that the MO6 octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. The results are discussed. (c) 2004 Elsevier B.V. All rights reserved. |
关键词 | local lattice distortion electron paramagnetic resonance (EPR) crystal and ligand-field theory Cr3+ KSc(MoO4)(2) RbIn(MoO4)(2) RbSC(MoO4)(2) |
DOI | 10.1016/j.saa.2004.06.047 |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Spectroscopy |
WOS类目 | Spectroscopy |
WOS记录号 | WOS:000227852200032 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/82978 |
通讯作者 | Zheng, WC |
作者单位 | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Flying Inst China, Dept Phys Civil Aviat, Guanghan 618307, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, WC,Qing, Z,Wu, XX,et al. EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2005,61(6):1243-1246. |
APA | Zheng, WC,Qing, Z,Wu, XX,&Yang, M.(2005).EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,61(6),1243-1246. |
MLA | Zheng, WC,et al."EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 61.6(2005):1243-1246. |
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