Thermal transition of electrochemically synthesized polyaniline

doi:10.1016/j.polymdegradstab.2006.04.027

IMR OpenIR

	Thermal transition of electrochemically synthesized polyaniline
	Luo, Kun ; Shi, Nanlin ; Sun, Chao
通讯作者	Luo, Kun(kun.luo@manchester.ac.uk)
	2006-11-01
发表期刊	POLYMER DEGRADATION AND STABILITY
ISSN	0141-3910
卷号	91 期号:11 页码:2660-2664
摘要	The thermal stability of polyaniline (PAni) is of great importance in commercial applications. PAni and its emeraldine base form (PAni-EB) were electrochemically synthesized and subjected to thermogravimetric analysis (TGA) in inert atmosphere, which illustrated that the dopant HClO4 could act as the oxidizing agent at elevated temperature and caused serious decomposition of PAni. Combined with differential scanning calorimetry (DSC), in-situ X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) analyses, the crosslinking reaction among PAni-EB molecules at about 250 degrees C was characterized, and the kinetic parameters were calculated by applying different heating rates in the DSC measurement. (c) 2006 Elsevier Ltd. All rights reserved.
关键词	polyaniline electrochemical synthesis thermal transition crosslinking reaction kinetic parameter
DOI	10.1016/j.polymdegradstab.2006.04.027
收录类别	SCI
语种	英语
WOS研究方向	Polymer Science
WOS类目	Polymer Science
WOS记录号	WOS:000241474300015
出版者	ELSEVIER SCI LTD
引用统计	被引频次：50[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/88248
专题	中国科学院金属研究所
通讯作者	Luo, Kun
作者单位	1.Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England 2.Chinese Acad Sci, Met Res Inst, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Luo, Kun,Shi, Nanlin,Sun, Chao. Thermal transition of electrochemically synthesized polyaniline[J]. POLYMER DEGRADATION AND STABILITY,2006,91(11):2660-2664.
APA	Luo, Kun,Shi, Nanlin,&Sun, Chao.(2006).Thermal transition of electrochemically synthesized polyaniline.POLYMER DEGRADATION AND STABILITY,91(11),2660-2664.
MLA	Luo, Kun,et al."Thermal transition of electrochemically synthesized polyaniline".POLYMER DEGRADATION AND STABILITY 91.11(2006):2660-2664.