Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6

doi:10.1016/j.scriptamat.2006.11.004

IMR OpenIR

	Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6
	Kang, Xiang-Dong; Wang, Ping; Cheng, Hui-Ming
通讯作者	Wang, Ping(pingwang@imr.ac.cn)
	2007-03-01
发表期刊	SCRIPTA MATERIALIA
ISSN	1359-6462
卷号	56 期号:5 页码:361-364
摘要	The effect of the dopant anion on thermodynamic tailoring in TiF3- and TiCl3-doped Na3AlH6 was investigated by pressure-composition desorption isotherm measurements. It was found that the dissociation pressure of the TiF3-doped hydride was substantially higher than that of the TiCl3-doped sample. This finding agrees well with the theoretically demonstrated thermodynamic modification arising upon F- substitution in the hydride lattice, thus providing direct experimental evidence to support functionality of F- anion. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
关键词	hydrogen storage sodium alanate catalysis thermodynamics
DOI	10.1016/j.scriptamat.2006.11.004
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000244109200010
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：35[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/89979
专题	中国科学院金属研究所
通讯作者	Wang, Ping
作者单位	Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Kang, Xiang-Dong,Wang, Ping,Cheng, Hui-Ming. Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6[J]. SCRIPTA MATERIALIA,2007,56(5):361-364.
APA	Kang, Xiang-Dong,Wang, Ping,&Cheng, Hui-Ming.(2007).Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6.SCRIPTA MATERIALIA,56(5),361-364.
MLA	Kang, Xiang-Dong,et al."Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6".SCRIPTA MATERIALIA 56.5(2007):361-364.