Influence of trace Ge on oxidation of liquid tin in atmosphere | |
Gong Guoliang; Xian Aiping | |
Corresponding Author | Xian Aiping(ap.xian@imr.ac.cn) |
2007-07-01 | |
Source Publication | ACTA METALLURGICA SINICA
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ISSN | 0412-1961 |
Volume | 43Issue:7Pages:759-763 |
Abstract | The oxidation behviours of liquid tin with and without trace Ge at 250 degrees C in atmosphere were studied by both observation and removing dross from the surface periodically. The surface composition, atom's valence state and the surface morphology were researched by both XPS and SEM. The results showed that the liquid tin has an excellent oxidation resistance in atmosphere when the Ge content was up to 0.01% (mass fraction). XPS analysis presents that trace Ge segregated highly on surface, and existed as an oxide with positive four valences. Based on the results, a mechanism why trace Ge can improve the oxidation resistance of liquid tin was suggested, that is the trace Ge rapidly segregated on the surface of liquid tin when it was melting, then it formed a layer of protective and density oxide film to resist future oxidation of liquid tin in atmosphere. |
Keyword | tin oxidation liquid metals solder |
Indexed By | SCI |
Language | 英语 |
WOS Research Area | Metallurgy & Metallurgical Engineering |
WOS Subject | Metallurgy & Metallurgical Engineering |
WOS ID | WOS:000248548200017 |
Publisher | SCIENCE CHINA PRESS |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/90173 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Xian Aiping |
Affiliation | Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Gong Guoliang,Xian Aiping. Influence of trace Ge on oxidation of liquid tin in atmosphere[J]. ACTA METALLURGICA SINICA,2007,43(7):759-763. |
APA | Gong Guoliang,&Xian Aiping.(2007).Influence of trace Ge on oxidation of liquid tin in atmosphere.ACTA METALLURGICA SINICA,43(7),759-763. |
MLA | Gong Guoliang,et al."Influence of trace Ge on oxidation of liquid tin in atmosphere".ACTA METALLURGICA SINICA 43.7(2007):759-763. |
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