| Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)(6)]SnCl6 single crystal | |
| Mao Ai-Jie; Kuang Xiao-Yu; Tan Xiao-Ming; Wang Hui; Li Ju-Fen | |
| Corresponding Author | Kuang Xiao-Yu(scu_kxy@163.com) |
| 2007-07-01 | |
| Source Publication | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| ISSN | 1386-1425 |
| Volume | 67Issue:3-4Pages:890-893 |
| Abstract | The relationship between the impurity structures and the electron paramagnetic resonance (EPR) parameters D, (a-F) have been studied by diagonalizing the complete energy matrices for Mn2+ ion in [Mg(H2O)(6)]SnCl6 single crystal in a trigonal ligand field within a weak-field-representation. It is shown that the local lattice structure around Mn2+ ion in [Mg(H2O)(6)]SnCl6 exhibits an elongation distortion which is different at 290 K and 77 K. The local structure parameters R = 2.223 +/- 0.027 angstrom, theta = 52.966 +/- 0.004 degrees and R = 2.205 +/- 0.030 angstrom, theta = 53.155 +/- 0.047 degrees for Mn2+ ion in [Mg(H2O)(6)]SnCl6 are determined at different temperatures 290 K and 77 K, respectively, and EPR parameters D and (a-F) can also get a satisfactory explanation simultaneously. (C) 2006 Elsevier B.V. All rights reserved. |
| Keyword | ligand-field theory EPR parameter [Mg(H2O)(6)]SnCl6 : Mn2+ system local lattice structure |
| DOI | 10.1016/j.saa.2006.09.005 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Spectroscopy |
| WOS Subject | Spectroscopy |
| WOS ID | WOS:000247452400051 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/90487 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Kuang Xiao-Yu |
| Affiliation | 1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Mao Ai-Jie,Kuang Xiao-Yu,Tan Xiao-Ming,et al. Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)(6)]SnCl6 single crystal[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):890-893. |
| APA | Mao Ai-Jie,Kuang Xiao-Yu,Tan Xiao-Ming,Wang Hui,&Li Ju-Fen.(2007).Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)(6)]SnCl6 single crystal.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,67(3-4),890-893. |
| MLA | Mao Ai-Jie,et al."Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)(6)]SnCl6 single crystal".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 67.3-4(2007):890-893. |
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