| Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal | |
| Gao, Ming-Liang1; Kuang, Xiao-Yu1,2; Li, Hui-Fang1; Wang, Huai-Qian1 | |
| Corresponding Author | Kuang, Xiao-Yu(scu_kuang@163.com) |
| 2009-07-01 | |
| Source Publication | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
 |
| ISSN | 0932-0784 |
| Volume | 64Issue:7-8Pages:511-517 |
| Abstract | A theoretical method for studying the inter-relationship between electronic and molecular structure is presented by means of complete energy matrices. As an application, the effects of temperature, concentration and hydrostatic pressure on the local structures of Ni2+ doped Zn(BF4)(2) center dot 6H(2)O crystal have been Studied. Our results show that the local lattice structures of [Ni(H2O)(6)](2+) coordination complex have expansion distortions as the temperature rises. Meanwhile, we find that the local structure parameter theta becomes smaller with the increasing concentration of Ni2+ ions doped in Zn(BF4)(2) center dot 6H(2)O crystal. Furthermore, the pressure dependence of theta and anisotropic g-factors are discussed and the relationship between zero-field splitting parameter D and Delta g is determined. |
| Keyword | Local Structure Zn(BF4)(2) center dot 6H(2)O:Ni2+ System Complete Energy Matrices |
| Funding Organization | National Natural Science Foundation of China ; Doctoral Education Fund of Education Ministry of China |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[10774103] ; Doctoral Education Fund of Education Ministry of China[20050610011] |
| WOS Research Area | Chemistry ; Physics |
| WOS Subject | Chemistry, Physical ; Physics, Multidisciplinary |
| WOS ID | WOS:000270164300015 |
| Publisher | VERLAG Z NATURFORSCH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/97163 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Kuang, Xiao-Yu |
| Affiliation | 1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 100016, Peoples R China |
| Recommended Citation GB/T 7714 | Gao, Ming-Liang,Kuang, Xiao-Yu,Li, Hui-Fang,et al. Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2009,64(7-8):511-517. |
| APA | Gao, Ming-Liang,Kuang, Xiao-Yu,Li, Hui-Fang,&Wang, Huai-Qian.(2009).Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,64(7-8),511-517. |
| MLA | Gao, Ming-Liang,et al."Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 64.7-8(2009):511-517. |
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