Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal

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	Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal
	Gao, Ming-Liang 1; Kuang, Xiao-Yu 1,2; Li, Hui-Fang 1; Wang, Huai-Qian 1
通讯作者	Kuang, Xiao-Yu(scu_kuang@163.com)
	2009-07-01
发表期刊	ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN	0932-0784
卷号	64 期号:7-8 页码:511-517
摘要	A theoretical method for studying the inter-relationship between electronic and molecular structure is presented by means of complete energy matrices. As an application, the effects of temperature, concentration and hydrostatic pressure on the local structures of Ni2+ doped Zn(BF4)(2) center dot 6H(2)O crystal have been Studied. Our results show that the local lattice structures of [Ni(H2O)(6)](2+) coordination complex have expansion distortions as the temperature rises. Meanwhile, we find that the local structure parameter theta becomes smaller with the increasing concentration of Ni2+ ions doped in Zn(BF4)(2) center dot 6H(2)O crystal. Furthermore, the pressure dependence of theta and anisotropic g-factors are discussed and the relationship between zero-field splitting parameter D and Delta g is determined.
关键词	Local Structure Zn(BF4)(2) center dot 6H(2)O:Ni2+ System Complete Energy Matrices
资助者	National Natural Science Foundation of China ; Doctoral Education Fund of Education Ministry of China
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[10774103] ; Doctoral Education Fund of Education Ministry of China[20050610011]
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Multidisciplinary
WOS记录号	WOS:000270164300015
出版者	VERLAG Z NATURFORSCH
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/97163
专题	中国科学院金属研究所
通讯作者	Kuang, Xiao-Yu
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 100016, Peoples R China
推荐引用方式 GB/T 7714	Gao, Ming-Liang,Kuang, Xiao-Yu,Li, Hui-Fang,et al. Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2009,64(7-8):511-517.
APA	Gao, Ming-Liang,Kuang, Xiao-Yu,Li, Hui-Fang,&Wang, Huai-Qian.(2009).Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,64(7-8),511-517.
MLA	Gao, Ming-Liang,et al."Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni2+ Doped Zn(BF4)(2) center dot 6H(2)O Crystal".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 64.7-8(2009):511-517.