Synthesis and photoluminescence properties of Eu2+ doped Sr9Sc(PO4)(7) phosphors for white light-emitting diodes | |
Dong, Xiaoling1,2; Zhang, Jiahua1; Zhang, Xia1; Hao, Zhendong1; Lv, Shaozhe1 | |
Corresponding Author | Zhang, Jiahua(zhangjh@ciomp.ac.cn) |
2014-05-01 | |
Source Publication | CERAMICS INTERNATIONAL
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ISSN | 0272-8842 |
Volume | 40Issue:4Pages:5421-5423 |
Abstract | A series of Eu2+-activated Sr9Sc(PO4)(7) yellowish-green emitting phosphors were synthesized by conventional solid-state reaction. The photoluminescence (PL) properties and concentration quenching mechanism of the as-prepared phosphors were investigated. The emission spectrum exhibits a broad and asymmetric band peaking at 510 nm, which corresponds to the 4f(6)5d(1) -> 4f(7) transition of Eu2+. The excitation spectrum exhibits a broad band extending from 250 to 450 nm, which matches well with the.emission of near ultraviolet (n-UV) chips (350 430 nm). Non-radiative transitions between Eu2+ ions in the Sr9Sc(PO4)(7) host have been demonstrated to be attributable to dipole dipole interactions, and the critical distance was calculated to be 23.1 A. These results indicate that Sr9Sc(PO4)(7):Eu2+ phosphor could serve as a promising candidate for application in n-UV white-light LEDs. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved. |
Keyword | Powder: solid state reaction Spectroscopy Optical properties |
Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Jilin province |
DOI | 10.1016/j.ceramint.2013.10.124 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[10834006] ; National Natural Science Foundation of China[51172226] ; National Natural Science Foundation of China[61275055] ; National Natural Science Foundation of China[11274007] ; National Natural Science Foundation of China[11174278] ; Natural Science Foundation of Jilin province[201205024] |
WOS Research Area | Materials Science |
WOS Subject | Materials Science, Ceramics |
WOS ID | WOS:000332268200043 |
Publisher | ELSEVIER SCI LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/125872 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Zhang, Jiahua |
Affiliation | 1.Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Luminescence & Applicat, Changchun 130033, Peoples R China 2.Grad Sch Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Dong, Xiaoling,Zhang, Jiahua,Zhang, Xia,et al. Synthesis and photoluminescence properties of Eu2+ doped Sr9Sc(PO4)(7) phosphors for white light-emitting diodes[J]. CERAMICS INTERNATIONAL,2014,40(4):5421-5423. |
APA | Dong, Xiaoling,Zhang, Jiahua,Zhang, Xia,Hao, Zhendong,&Lv, Shaozhe.(2014).Synthesis and photoluminescence properties of Eu2+ doped Sr9Sc(PO4)(7) phosphors for white light-emitting diodes.CERAMICS INTERNATIONAL,40(4),5421-5423. |
MLA | Dong, Xiaoling,et al."Synthesis and photoluminescence properties of Eu2+ doped Sr9Sc(PO4)(7) phosphors for white light-emitting diodes".CERAMICS INTERNATIONAL 40.4(2014):5421-5423. |
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