| Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films | |
| Gao, Zhaoqing1; Cao, Jinwei1; Wang, Chen1; Chen, Yinbo2,3; Muzammal, Hussain Muhammad1; Wang, Weiqiang1; Sun, Hao1; Ma, Haitao1; Wang, Yunpeng1 | |
| Corresponding Author | Ma, Haitao(htma@dlut.edu.cn) ; Wang, Yunpeng(yunpengw@dlut.edu.cn) |
| 2020-01-23 | |
| Source Publication | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| ISSN | 1434-1948 |
| Volume | 2020Issue:3Pages:261-268 |
| Abstract | In this paper, in order to explore the effect of the preferential orientation of Cu on the preparation of robust anodized Cu2O films, three types of Cu substrates with three different preferential crystal plane orientation [(111), (200), (220)] are employed. First-Principles calculation is employed to calculate the surface energy of different Cu crystalline planes by the software of DACAPO, which is conducted by the plane-wave pseudo-potential method. The influence of the preferential plane orientation of Cu on the anodized oxidation reaction process and the morphology of anodized CuxO films has been discussed in detail. The results indicate that the morphology of anodized CuxO films depends on the preferential exposing plane orientation of Cu substrates under the same anodized oxidation condition. The high surface energy of Cu makes Cu atoms release more easily from lattices, leading to more different active-reaction sites. |
| Keyword | Electrochemistry Copper Kinetics Reaction rate Surface chemistry |
| Funding Organization | Natural Science Foundation of Liaoning Province, China ; Fundamental Research Funds for the Central Universities China |
| DOI | 10.1002/ejic.201901084 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Natural Science Foundation of Liaoning Province, China[20170540163] ; Fundamental Research Funds for the Central Universities China[DUT18GJ207] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Inorganic & Nuclear |
| WOS ID | WOS:000506126500001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/136407 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Ma, Haitao; Wang, Yunpeng |
| Affiliation | 1.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Gao, Zhaoqing,Cao, Jinwei,Wang, Chen,et al. Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020,2020(3):261-268. |
| APA | Gao, Zhaoqing.,Cao, Jinwei.,Wang, Chen.,Chen, Yinbo.,Muzammal, Hussain Muhammad.,...&Wang, Yunpeng.(2020).Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020(3),261-268. |
| MLA | Gao, Zhaoqing,et al."Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2020.3(2020):261-268. |
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