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Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films
Gao, Zhaoqing1; Cao, Jinwei1; Wang, Chen1; Chen, Yinbo2,3; Muzammal, Hussain Muhammad1; Wang, Weiqiang1; Sun, Hao1; Ma, Haitao1; Wang, Yunpeng1
Corresponding AuthorMa, Haitao(htma@dlut.edu.cn) ; Wang, Yunpeng(yunpengw@dlut.edu.cn)
2020-01-23
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Volume2020Issue:3Pages:261-268
AbstractIn this paper, in order to explore the effect of the preferential orientation of Cu on the preparation of robust anodized Cu2O films, three types of Cu substrates with three different preferential crystal plane orientation [(111), (200), (220)] are employed. First-Principles calculation is employed to calculate the surface energy of different Cu crystalline planes by the software of DACAPO, which is conducted by the plane-wave pseudo-potential method. The influence of the preferential plane orientation of Cu on the anodized oxidation reaction process and the morphology of anodized CuxO films has been discussed in detail. The results indicate that the morphology of anodized CuxO films depends on the preferential exposing plane orientation of Cu substrates under the same anodized oxidation condition. The high surface energy of Cu makes Cu atoms release more easily from lattices, leading to more different active-reaction sites.
KeywordElectrochemistry Copper Kinetics Reaction rate Surface chemistry
Funding OrganizationNatural Science Foundation of Liaoning Province, China ; Fundamental Research Funds for the Central Universities China
DOI10.1002/ejic.201901084
Indexed BySCI
Language英语
Funding ProjectNatural Science Foundation of Liaoning Province, China[20170540163] ; Fundamental Research Funds for the Central Universities China[DUT18GJ207]
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000506126500001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/136407
Collection中国科学院金属研究所
Corresponding AuthorMa, Haitao; Wang, Yunpeng
Affiliation1.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Gao, Zhaoqing,Cao, Jinwei,Wang, Chen,et al. Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020,2020(3):261-268.
APA Gao, Zhaoqing.,Cao, Jinwei.,Wang, Chen.,Chen, Yinbo.,Muzammal, Hussain Muhammad.,...&Wang, Yunpeng.(2020).Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020(3),261-268.
MLA Gao, Zhaoqing,et al."Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2020.3(2020):261-268.
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