Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films

doi:10.1002/ejic.201901084

IMR OpenIR

	Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films
	Gao, Zhaoqing 1; Cao, Jinwei 1; Wang, Chen 1; Chen, Yinbo 2,3; Muzammal, Hussain Muhammad 1; Wang, Weiqiang 1; Sun, Hao 1; Ma, Haitao 1; Wang, Yunpeng 1
通讯作者	Ma, Haitao(htma@dlut.edu.cn) ; Wang, Yunpeng(yunpengw@dlut.edu.cn)
	2020-01-23
发表期刊	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN	1434-1948
卷号	2020 期号:3 页码:261-268
摘要	In this paper, in order to explore the effect of the preferential orientation of Cu on the preparation of robust anodized Cu2O films, three types of Cu substrates with three different preferential crystal plane orientation [(111), (200), (220)] are employed. First-Principles calculation is employed to calculate the surface energy of different Cu crystalline planes by the software of DACAPO, which is conducted by the plane-wave pseudo-potential method. The influence of the preferential plane orientation of Cu on the anodized oxidation reaction process and the morphology of anodized CuxO films has been discussed in detail. The results indicate that the morphology of anodized CuxO films depends on the preferential exposing plane orientation of Cu substrates under the same anodized oxidation condition. The high surface energy of Cu makes Cu atoms release more easily from lattices, leading to more different active-reaction sites.
关键词	Electrochemistry Copper Kinetics Reaction rate Surface chemistry
资助者	Natural Science Foundation of Liaoning Province, China ; Fundamental Research Funds for the Central Universities China
DOI	10.1002/ejic.201901084
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Liaoning Province, China[20170540163] ; Fundamental Research Funds for the Central Universities China[DUT18GJ207]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000506126500001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/136407
专题	中国科学院金属研究所
通讯作者	Ma, Haitao; Wang, Yunpeng
作者单位	1.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Gao, Zhaoqing,Cao, Jinwei,Wang, Chen,et al. Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020,2020(3):261-268.
APA	Gao, Zhaoqing.,Cao, Jinwei.,Wang, Chen.,Chen, Yinbo.,Muzammal, Hussain Muhammad.,...&Wang, Yunpeng.(2020).Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2020(3),261-268.
MLA	Gao, Zhaoqing,et al."Effect of Cu Preferential Orientation on the Microstructure and Properties of Anodized CuxO Films".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2020.3(2020):261-268.