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In-situ reaction synthesis and mechanical properties of quaternary MAX phase (Cr2/3Ti1/3)(3)AlC2
Liu, Zhimou1; Yang, Jia2; Qian, Yuhai1; Xu, Jingjun1; Zuo, Jun1; Li, Meishuan1
Corresponding AuthorQian, Yuhai(yhqian@imr.ac.cn) ; Li, Meishuan(mshli@imr.ac.cn)
2020-10-01
Source PublicationCERAMICS INTERNATIONAL
ISSN0272-8842
Volume46Issue:14Pages:22854-22860
AbstractBulk quaternary MAX phase (Cr2/3Ti1/3)(3)AlC2 was synthesized by in-situ reaction/hot pressing method using Cr, Ti, Al, and C powders as starting materials. The involved reaction routes during hot-pressing were determined according to XRD and SEM/EDS analysis results. The possible chemical reactions involved during hot pressing process were proposed. It was revealed that the desired (Cr2/3Ti1/3)(3)AlC2 was formed via the reaction between intermediate products of ternary MAX Cr2AlC and carbide TiC, providing another path for the preparation of high order MAX phase. Tests of mechanical properties suggested that the Vickers hardness of (Cr2/3Ti1/3)(3)AlC2 was 5.6 GPa, higher than that of the ternary MAX phase Ti3AlC2. Its flexural and compressive strength were determined to be 493 MPa and 1407 MPa at room temperature, respectively. Flexural strength maintained a relatively high level of 424 MPa up to 1000 degrees C, about 90% of that at room temperature. The dependence of elastic modulus on increasing temperatures exhibited similar tendency to that of flexural strength. The as-synthesized (Cr2/3Ti1/3)(3)AlC2, a unique quaternary layered nano-laminated carbide, was a promising high temperature structural material with its attractively comprehensive properties.
KeywordQuaternary MAX Phase (Cr2/3Ti1/3)(3)AlC2 Reaction route Mechanical property
Funding OrganizationNational Natural Science Foundation of China, China
DOI10.1016/j.ceramint.2020.06.055
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China, China[51271191] ; National Natural Science Foundation of China, China[51571205]
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Ceramics
WOS IDWOS:000558707400110
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/140256
Collection中国科学院金属研究所
Corresponding AuthorQian, Yuhai; Li, Meishuan
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
2.Hunan Univ Technol, Sch Mech Engn, Zhuzhou 412007, Peoples R China
Recommended Citation
GB/T 7714
Liu, Zhimou,Yang, Jia,Qian, Yuhai,et al. In-situ reaction synthesis and mechanical properties of quaternary MAX phase (Cr2/3Ti1/3)(3)AlC2[J]. CERAMICS INTERNATIONAL,2020,46(14):22854-22860.
APA Liu, Zhimou,Yang, Jia,Qian, Yuhai,Xu, Jingjun,Zuo, Jun,&Li, Meishuan.(2020).In-situ reaction synthesis and mechanical properties of quaternary MAX phase (Cr2/3Ti1/3)(3)AlC2.CERAMICS INTERNATIONAL,46(14),22854-22860.
MLA Liu, Zhimou,et al."In-situ reaction synthesis and mechanical properties of quaternary MAX phase (Cr2/3Ti1/3)(3)AlC2".CERAMICS INTERNATIONAL 46.14(2020):22854-22860.
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