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Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst
Li, Xiaolin1,2; Zhang, Liang1; Sun, Yinyong3
通讯作者Zhang, Liang(zhangliang@szpt.edu.cn) ; Sun, Yinyong(yysun@hit.edu.cn)
2020-09-01
发表期刊CATALYSTS
卷号10期号:9页码:10
摘要A titanium-chromium-oxide catalyst was prepared by a facile calcination of titanium-modified MIL-101(Cr). The resulting material, possessing a surface area of 60 m(2)g(-1)and a titania content of 50.0 wt%, can be directly used as the catalyst for oxidative desulfurization (ODS) reaction of dibenzothiophene (DBT). This novel ODS catalyst can remove 900 ppm sulfur-containing compounds in a reaction time of 30 min at 60 degrees C. The experimental results showed that the specific activity increased with the titanium content. The specific activity of the catalyst with 50%Ti reached 129 mu mol/m(2), which was much higher than that of reported Ti-based catalysts.
关键词MIL-101(Cr) anatase titania DBT oxidative desulfurization
资助者Post-Doctoral Foundation Project of Shenzhen Polytechnic ; Guangdong Basic and Applied Basic Research Foundation ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic
DOI10.3390/catal10091091
收录类别SCI
语种英语
资助项目Post-Doctoral Foundation Project of Shenzhen Polytechnic[6019330009K0] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515110532] ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic[6019271003K]
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000580563000001
出版者MDPI
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/141080
专题中国科学院金属研究所
通讯作者Zhang, Liang; Sun, Yinyong
作者单位1.Shenzhen Polytech, Postdoctoral Innovat Pract Base, Inst Intelligent Mfg Technol, Shenzhen 518055, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
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GB/T 7714
Li, Xiaolin,Zhang, Liang,Sun, Yinyong. Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst[J]. CATALYSTS,2020,10(9):10.
APA Li, Xiaolin,Zhang, Liang,&Sun, Yinyong.(2020).Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst.CATALYSTS,10(9),10.
MLA Li, Xiaolin,et al."Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst".CATALYSTS 10.9(2020):10.
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