Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis

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	Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis
	S. C. Wu; G. D. Wen; X. M. Liu; B. W. Zhong; D. S. Su
	2014
发表期刊	Chemcatchem
ISSN	1867-3880
卷号	6 期号:6 页码:1558-1561
摘要	The role of different oxygen functional groups on a carbon catalyst was studied in the reduction of nitrobenzene by using a series of model molecules. The carbonyl and hydroxyl groups played important roles, which may be ascribed to their ability to activate hydrazine. In comparison, the ester, ether, and lactone groups seemed to be inactive, whereas the carboxylic group had a negative effect. The reaction occurred most likely through a direct route, during which nitrosobenzene may be converted directly into aniline.
部门归属	[wu, shuchang ; wen, guodong ; zhong, bingwei ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [wu, shuchang] chinese acad sci, grad univ, beijing 100049, peoples r china. [liu, xiumei] chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. ; su, ds (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china. ; dssu@imr.ac.cn
关键词	Active Sites Carbocatalysis Model Catalyst Reaction Mechanisms Reduction Oxidative Dehydrogenation Graphene Oxide Carbon Nanotubes Nitro-compounds Aerobic Oxidation Graphite Oxide N-butane Chemistry Efficient
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语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/73446
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	S. C. Wu,G. D. Wen,X. M. Liu,et al. Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis[J]. Chemcatchem,2014,6(6):1558-1561.
APA	S. C. Wu,G. D. Wen,X. M. Liu,B. W. Zhong,&D. S. Su.(2014).Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis.Chemcatchem,6(6),1558-1561.
MLA	S. C. Wu,et al."Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis".Chemcatchem 6.6(2014):1558-1561.